首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
Enrichment of trace elements in groundwater poses considerable risks to human health. The concentrations of seven trace elements (Cr, Mn, Ni, Cu, Zn, Cd, and Pb) in 34 samples of shallow groundwater from the study area were estimated. We assessed the concentrations of the trace elements and health risks with statistical analysis and the US Environment Protection Agency (USEPA) model. The results showed that the mean concentrations of trace elements decreased as follows: Mn > Zn > Ni > Cr > Cu > Cd > Pb. Apart from Mn at one sampling point, the concentrations of all trace elements were below the guideline values of the World Health Organization for drinking water. Correlation and cluster analysis indicated that the trace elements fell into groups, with Ni and Cu in one group, and Mn, Zn, and Cd in another, which suggested that the trace elements grouped together had similar sources. The total non-carcinogenic risk values ranged from 8.52 × 10?4 to 1.27 × 10?1. The total carcinogenic risk caused by Cr and Cd averaged 1.62 × 10?6, which exceeded the acceptable level of 1 × 10?6 recommended by the USEPA. The carcinogenic risk of Cr accounted for 75.93% of Rtotal.  相似文献   

2.
The investigation revealed the adverse health threats on human beings from toxic metals via ingestion of seafood from two contaminated sites in Odisha. Bioaccumulation through food chain was presented as tissue metal concentrations. The non-carcinogenic and carcinogenic health hazards were estimated by Target Hazard Quotient (THQ) and Target Cancer Risk (TCR) following USEPA referred safe metal intake limit. THQ of Metals like Mn, Ni, Cd, Pb in both sites showed >1, indicating a severe non carcinogenic health threat to humans from the investigated metals. THQ of Cu, Zn, Fe, Cr and Hg showed < 1, implying the least possible deleterious health effects. Cr was the most significant carcinogenic pollutant in both sites. The marine fish consumption of Dhamra site might cause extra 7 cases of cancer per 10000 populations due to higher Cr level (cancer risk 6.7 × 10?3). Carcinogenic risk of Ni and Pb were below the tolerable range of 10E-4. The presence of Cd in sea foods elevated cancer risks in both sites. The metal pollution index (MPI) indicated, the highest toxic metal bio accumulation was contributed by Arius arius species. Ilisha megaloptera and Lates calcarifer from Dhamra and Puri showed highest hazard index (HI) suggesting unaccountable non-carcinogenic health threat.  相似文献   

3.
The objective of this study is the evaluation of health risk of heavy metals in soils of urban community gardens of Baghdad City in Iraq. The soil samples were collected from 14 community gardens and analyzed for Cd, Cr, Cu, Ni, Pb and Zn. The non-carcinogenic hazard index (HI) and carcinogenic risk index (RI) were utilized to evaluate human health risk of heavy metals. The health hazard evaluation showed that there is no non-carcinogenic hazard in light of the fact that the HI values were beneath the threshold value (HI < 1). The HI for children and adults has a descending order of Cd < Cr < Cu < Ni < Pb < Zn. The carcinogenic RI values for Cd, Cr and Ni were over the unacceptable threshold value (RI < 1 × 10?4), demonstrating that there is a serious carcinogenic risk for children and adults in the study area. The carcinogenic RI for children and adults has a descending order of Cr < Cd < Ni. These findings give environment administrators and leaders data on whether therapeutic activities are required to decrease exposure.  相似文献   

4.
A total of 195 farmland soil samples were collected in Yanqi Basin, Xinjiang, northwest China, and the concentrations of As, Cd, Cr, Cu, Ni, Pb, and Zn were analyzed for their concentrations and pollution levels using the Nemerow comprehensive index. The health risk assessment model introduced by USEPA was utilized to evaluate the human health risks of heavy metals. Results indicated that the average concentrations of these seven metals were lower than the allowed soil environmental quality standards of China, while the average concentrations of Cd, Cr, Ni, Pb and Zn exceeded the background values of irrigation soils in Xinjiang. The average contamination factor (CF) for Pb indicated the heavy pollution, whereas the CF for Cd, Zn, Ni, Cu and Cr indicated the moderate pollution. The average PLI of heavy metals indicated the low pollution. The non-carcinogenic hazard index were below the threshold values, and the total carcinogenic risks due to As and Cr were within the acceptable range for both children and adults. As and Pb were the main non-carcinogenic factors, while As was the main carcinogenic factor in the study area. Special attentions should be paid to these priority control metals in order to target the lowest threats to human health.  相似文献   

5.
This study investigated heavy metals concentration in groundwater in six coastal communities in Gokana, Rivers State, namely, Gbe, K-Dere, B-Dere, Mogho, Kpor and Bodo City and the human health risk posed to the local populace via ingestion and dermal contact using non-carcinogenic and carcinogenic health risk assessment. The mean values of the heavy metals ranged between 0.02–0.86, 0.16–0.19, 0.03–0.10, 0.02–0.03 and 0.01–0.17 for Mn, Ni, Pb, Cd and Cr, respectively. The heavy metals were above the drinking water quality recommended limits in all the study sites. Estimations of average daily dose (ADD) and dermal absorbed dose (DAD) health risk indicates that Mn, Ni and Pb posed human health risk via ingestion contact pathway. However, hazard index (HI) values of Cd and Cr for ingestion pathway were >1.0 and the estimated Lifetime of Carcinogenic Risks (LTCR) for Ni, Cd and Cr exceeded the predicted lifetime risk for carcinogens of 10?6 from ingestion pathway. Furthermore, there were more appreciable risk from Ni and Cr in the study sites as LTCR value in most sites were >10?4. This study indicates possible non-carcinogenic and carcinogenic human health hazard from groundwater consumption in Gokana via oral ingestion.  相似文献   

6.
Abstract

A total of 83 dust samples were collected from the streets of Urumqi city in NW China and analyzed for the concentrations of As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, and Zn elements. The spatial distribution, contamination levels, main sources, and potential health risks of these trace elements were determined based on geostatistical analysis, geo-accumulation index, multivariate analysis, and the health risk assessment model introduced by the USEPA, respectively. The obtained results indicate that the average concentrations of Cd, Cr, Cu, Hg, Ni, Pb, and Zn exceed the corresponding background values determined in Xinjiang soils by factors of 2.0, 1.35, 1.38, 8.24, 1.28, 2.09, and 3.26, respectively. The spatial distribution patterns of the nine trace elements in street dust were found to be substantially heterogeneous, and the contamination level decreased in the following order: Hg?>?Zn?>?Pb?>?Cd?>?Cr?>?Cu?>?As?>?Ni?>?Mn. Based on the identified concentrations, the collected dust samples were found to be moderately polluted by Hg, and not polluted by As, Cr, Cu, Mn, and Ni. The remaining elements, Cd, Pb, and Zn lie on the borderline between non-pollution and moderate pollution levels. Furthermore, it was shown that Mn and Zn in street dusts originate from both, natural and anthropogenic sources, while As, Cd, Cr, Cu, Hg, Ni, and Pb are mainly produced by anthropogenic sources. Overall, the carcinogenic and non-carcinogenic health risks of the analyzed elements, instigated primarily by oral ingestion of street dusts, were found to be within the acceptable range for both, children and adults. As and Cr are the main non-carcinogenic elements, whereas Cr is the major carcinogenic element among the investigated dust-bound metals in the study area.  相似文献   

7.
Heavy metals (Al, Cd, Co, Cr, Cu, Fe, Pb, Zn) in surface soil of Klang district were determined and multivariate analysis was used to understand their potential sources. The total and bioavailability of concentrations were used in identifying the potential risks to the ecology and human health. The means for the total heavy metal concentrations were found to be in the order of Fe > Al > Zn > Pb > Cu > Cr > Co > Cd, while the means for the bioavailability concentrations were found to be in the order of Al > Fe > Zn > Cu > Co > Cd > Pb > Cr. Principal Component Analysis showed Principal Component 1 as being of natural origin whereas Principal Components 2, 3, and 4 were associated with mixed anthropogenic sources, such as traffic and industrial emissions, organic matter, and granulometric fractions. Potential ecological risk assessment indicated an overall low ecological risk. Spatial assessment of non-carcinogenic risks showed that the Hazard Index values were more than one in Johan Setia, due to biomass burning of peat swamps exploited for agricultural development. While for spatial assessment of carcinogenic risks, the Lifetime Cancer Risk values were in the limit (1 × 10?5), indicating low cancer inducing risks. Nevertheless, with intense development pressure in the Klang district could overlap pollution inputs in the future.  相似文献   

8.
Abstract

The purpose of the study was to acquire the source and evaluate the risk posed by heavy metals in road dust of steel industrial city (Anshan), Liaoning, Northeast China. Potential ecological risk index (RI), pollution index (PI) and geo-accumulation index (Igeo) were applied to evaluate the heavy metal pollution level, and the carcinogenic risk (RI) and hazard index (HI) were calculated to estimate the human health risk. The geographic information system maps clearly reveal the hot spots of heavy metal spatial distribution. Principle component analysis (PCA) and cluster analysis (CA) classified heavy metals into three groups. The metal Zn and Pb originate from the traffic emission, while Cd, Cr, Fe, Mn, Ni and Sb primarily come from industrial activities. These two pathways were the major source of heavy metals pollution by positive matrix factorization (PMF). The Igeo and PI values of heavy metals were decreased in the following order: Cd?>?Sb?>?Zn?>?Fe?>?Pb?>?Cu?>?Cr?>?Sn?>?Mn?>?Ni. The RI index showed the heavy metals were moderate to very high potential ecological risk. The HI values for children and adults presented a decreasing order of Cr?>?Pb?>?Ni?>?Cu?>?Cd?>?Zn. The HI also predicted a possibility of non-carcinogenic risk for children living in urban areas in comparison with adults.  相似文献   

9.
The pollution and potential health risk due to lifetime exposure to heavy metals in urban soil of China were evaluated, based on the urban soil samples collected from published papers from 2005 to 2014. The contamination levels were in the order of Cd > Hg > Cu > Zn > Pb >As > Ni > Cr, and Hg and Cd fell into the category of “moderately contaminated” to “heavily contaminated.” The non-carcinogenic risk for different populations varied greatly, among which children faced high risk, and then the adult female and adult male followed. The hazard index (non-carcinogenic risk) higher than 1.00 occurred in Shanghai, Gansu, Qinghai, Hunan, and Anhui, whereas most of those in northern and western China had low risks. For the carcinogenic risk, Anhui and Ningxia provinces had urban soils exceeding the safe reference (1 × 10?6–1 × 10?4). Qinghai and Gansu had high carcinogenic risks since their risk indexes were much closer to the reference, and the others were in low risk.  相似文献   

10.
We analysed the concentrations of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn in the water, sediments, fish and plants of the River Hindon, U.P., India, at seven sampling stations, in the year 1982. Considerable variation in concentration between water, sediments, fish and plants were noted. The concentration in the water was in the order Fe > Zn > Cr > Mn > Cu > Pb > Ni > Co > Cd, in the sediments, Fe > Mn > Zn > Ni > Cr > - Co > Cu > Pb > Cd; in a fish (Heteropnuestes fossilis) Fe > Zn > Mn > Pb > Ni > Co > Cu > Cd > Cr, and in a plant (Eicchornia crassipes) Fe > Mn > Zn > Ni > Cu > Cr > Pb > Co > Cd.  相似文献   

11.
Accumulation of different metals and metalloids was assessed in two vegetables radish (Raphanus sativus L.) and spinach (Spinacea oleracea L.) irrigated with domestic wastewater in the peri-urban areas of Khushab City, Pakistan. In general, the metal and metalloid concentrations in radish and spinach were higher at site-II treated with sewage water than those found at site-I treated with canal water. In case of radish at both sites the levels of metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, and Pb) were below the permissible level except those of Mn, Ni, Mo, Cd, and Pb. At both sites, the transfer factor ranged from 0.047–228.3 mg kg?1 with Cr having the highest transfer factor. The metal pollution index in soil was in the following order: As > Fe > Ni > Zn > Cd > Mo > Se > Co > Pb > Mn > Cr > Cu, respectively. While in case of spinach at both sites, the concentrations of metals and metalloids in vegetable samples irrigated with canal and sewage water were observed below the permissible level except Mn, Ni, Zn, Mo, and Pb. At both sites, the transfer factor ranged from 0.038–245.4 mg kg?1 with Cr having the highest transfer factor. The metal pollution index in soil was in the following order: Cd > Ni > Co > Se > Mn > Zn > Mo > Pb > Fe > Cr > As > Cu, respectively.  相似文献   

12.
This study investigated the concentrations of selected metals (Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Pb, Sr, and Zn) in freshwater source lakes in Pakistan and assessed the preliminary health risks associated with them. Water samples were collected from Khanpur and Simly Lakes and analyzed for the metals using flame atomic absorption spectrophotometry. Major contributions were noted for Ca, K, Mg, and K; however, the measured levels of Cd, Co, Cr, and Pb were many times higher than the permissible national/international guideline values. The risk characterization revealed that hazard quotient (HQing) and hazard index (HIing) values exceeded the acceptable limit unity, indicating non-carcinogenic risk to the recipients via oral intake of contaminated water. The carcinogenic risk (CRing) via ingestion route for Cd, Cr, and Pb was found much greater than the acceptable limit (10–6). Overall, Cd, Co, Cr, and Pb were the major contributors to potential adverse health risk to the inhabitants. Multivariate analysis demonstrated anthropogenic intrusions of the metals in both lakes. The study clearly indicated that there was gross contamination of water in both lakes, so special attention should be paid to manage the pollution sources of metals.  相似文献   

13.
为探讨油茶(Camellia oleifera)产地土壤和油茶果实中金属元素分布和富集特征,在油茶果实成熟期,对浙江5个油茶产地土壤及油茶果实中金属元素进行污染分析和富集能力评价。结果表明,浙江油茶产地土壤中Pb、Cr、Cd、As、Hg、Ni、Cu和Zn含量低于农用地土壤污染风险筛选值,综合污染等级为安全。个别产区常山县土壤中As、Ni、Cu和江山县土壤中Pb、Cr、Fe含量显著高于其他产地;常山和建德土壤中Cd单因子污染指数分别为0.93和0.81,处于污染警戒线。Cr、Ni、Cu、Zn主要分布在油茶籽中,Hg主要分布在壳中,Pb、Cd、As、Fe和Mn主要分布在青皮中。油茶籽中Cu、Fe、Mn的富集系数大于0.4,吸收能力强,Ni、Zn的富集系数小于0.4,具有一定吸收能力,Pb、Cr、Cd、As和Hg的富集系数小于0.1,吸收能力低;壳中Cu、Mn的富集系数大于0.4,吸收能力强,Fe的富集系数小于0.4,具有一定吸收能力,Pb、Cr、Cd、As、Hg、Ni、Zn的富集系数小于0.1,吸收能力低;青皮中Cu、Fe、Mn的富集系数大于0.4,吸收能力强,Pb、Cr、Cd、As、Hg、Ni、Zn的富集系数小于0.1,吸收能力低。浙江油茶主产区土壤质量安全,适合油茶种植。油茶果实对Cu、Fe、Mn有一定富集能力,对Pb、Cr、Cd、As和Hg无富集能力。  相似文献   

14.
Element contents and radical scavenging activity in commercial Yerba mate tea blends from Paraguay and Argentina were determined. The potential health risk for the consumers was also calculated. Element contents in Yerba mate was arranged as follows: K > Ca > Mg > Mn > Fe > Zn > Na > Cu > Ni > Cr > Pb > Cd (leaves and stalks) and K > Mg > Mn > Ca > Zn > Na > Fe > Cu > Ni > Cr > Pb > Cd (infusion). In total 73% of K, 69% of Mn, 15% of Ni and Cu, 9% of Cr, 8% of Zn, 7% of Mg, 6% of Pb, 3% of Na, 2% of Cd, 0.34% of Ca, and 0.13% of Fe were extracted from leaves and stalks to the brew. Yerba mate tea was characterized by very high antioxidant activity. Argentinean Yerba mate had slightly higher antioxidant activity than Paraguayan. The combined non-carcinogenic effect (HI values) for each infusion and for all three infusion were below 1, which indicated that daily consumption of Yerba mate tea infusions did not cause essential non-carcinogenic health risk. The daily consumption of Yerba mate infusions provided necessary elements in the amounts significantly below 1% of the Recommended Dietary Allowance (RDA) daily intake. The exception was amount of Mn in I infusion from the despalada kind of Yerba mate, which was equal to 1.43% of RDA for men and 1.82% of RDA for women.  相似文献   

15.
Health Risk Assessment of Heavy Metals in Urban Soil of Karachi,Pakistan   总被引:1,自引:0,他引:1  
The potential health risk due to lifetime exposure to copper, lead, chromium, zinc, and iron in urban soil of Karachi, Pakistan, was evaluated. Mean concentrations of Cu, Pb, Cr, Zn, and Fe in topsoil samples were 33.3 ± 12.8, 42.1 ± 55.8, 9.6 ± 4.2, 99.5 ± 37.3, and 908.4 ± 57.8 mg kg?1, respectively. A U.S. Environmental Protection Agency model was adopted for the carcinogenic and non-carcinogenic risk assessment from different exposure pathways. Risk assessment indicated that the overall results for the carcinogenic risk were insignificant. However, the carcinogenic risk from Pb due to oral ingestion of soil exceeded the value of 1 × 10?6, in some areas of the city. It indicates that the exposure to Pb-contaminated soil may cause adverse health effects in humans, especially in children. The Hazard Quotient (HQ) for different metals through ingestion and dermal pathways was also found to be less than 1. The combined Hazard Index (HI) for children through different routes of exposure was 8.9 times greater than for adults. It indicates that the children are more susceptible to non-carcinogenic health effects of trace metals compared to adults. Particularly, non-carcinogenic risk of Pb to children via oral ingestion needs special attention.  相似文献   

16.
This investigation was conducted to survey the levels of cadmium (Cd), lead (Pb), chromium (Cr), copper (Cu), zinc (Zn), and manganese (Mn) in polished rice collected at supermarkets located in Hengyang, China. The surveyed rice samples were grouped according to their production areas into four different groups—Hunan, Jiangxi, Jilin, and Thailand. The data showed that the highest means of Cd, Pb, Cr, Cu, Zn, and Mn contents were in rice samples produced from Hunan (0.215 mg/kg), Thailand (0.537 mg/kg), Hunan (0.348 mg/kg), Jiangxi (2.472 mg/kg), Thailand (17.259 mg/kg), and Jinlin (9.326 mg/kg), respectively. Average daily intake dose for the six elements through consumption of rice was lower than the oral reference dose. Although the hazard quotient values for all six elements were <1.0, hazard index values in all the production areas (except Thailand) were >1.0, and cancer risk (CR) and total CR values were >10?4, respectively. Certainly, there are inherent limitations for these health risk values, including actual ingestion rate, exposure duration, and bioavailability of heavy metals. These results indicate that long-term heavy metal exposure by consumption of rice in Hengyang could pose both potential non-carcinogenic and carcinogenic health risks to the local residents.  相似文献   

17.
In this study, the content characteristics, comprehensive pollution assessment, and morphological distribution characteristics of heavy metals (Mn, Cd, Cr, Pb, Ni, Zn, and Cu) were researched based on the processes of field investigation, sample collection, and experimental analysis. Results showed that the mean concentrations of Mn, Pb, Cr, Cu, Cd, Zn, and Ni in surface soils were 522.77, 22.56, 55.10, 25.41, 0.25, 57.02, and 48.47 mg kg?1, respectively. The surface soil from Sunan mining area was contaminated by Cu, Cd, and Ni in different degrees, and high CV values of Cd, Zn, Pb, and Ni were influenced by local human activities possibly. The evaluation results suggested that the mean Igeo values were in the sequence of Cd (0.657) > Ni (0.052) > Cu (?0.293) > Mn (?0.626) > Zn (?0.761) > Cr (?0.884) > Pb (?0.899). Besides, Cd was the most significant potential risk factor among all elements. Nevertheless, the Cd of bioavailable speciations with higher proportion had stronger migration and toxicity, and was more easier to be absorbed and enriched than other elements by some crops (e.g., vegetables, rice), and being at a relatively higher potential ecological risk in soil.  相似文献   

18.
The concentrations of metals (Mn, Pb, Fe, Zn, Cu, Cd,Co, Ni, Cr, Na, K, Ca, Mg) were determined in thegreen alga Ulva rigida, in the sediment andseawater of Thermaikos Gulf (Greece) during monthlysamplings in 1994–1995. This Gulf is the recipientof domestic and industrial effluents. Pb, Fe, Cu, Coand Cr concentrations in U. rigida at the studyarea were higher than those 13 years earlier andapparently came from different sources than those forZn, Cd and Ni. The relative abundance of metals inthe alga decreased in the order: Mg > Na > K >Ca > Pb > Fe > Mn > Zn > Cr, Cu > Ni >Co > Cd. Only Cu concentrations in the alga fromKalochori and Cd ones from Viamyl showed significantseasonal changes. Cu and Cd concentrations ingeneral followed the same pattern of variation, withminimum values in winter-spring. This pattern isdiscussed in relation to growth dynamics and tissueage. Only Pb concentrations in the alga showed asignificant positive correlation with concentrationsin the seawater. There were both positive andnegative correlations among some metals in the alga. It is concluded that U. rigida can be used as anindicator species, especially for Pb.  相似文献   

19.
The concentrations of nine metals were measured by atomic absorption spectrophotometry in surface sediments of three coastal creeks, namely, the Ifie, Egbokodo and Ubeji creeks, in the Niger Delta of Nigeria, from August 2012 to January 2013. The aim of the study was to provide information on the spatial and seasonal distribution patterns, degree of contamination, and ecological risks of metals in these sediments. The mean concentrations of the nine metals in these creek sediments ranged from 0.30 to 3.20?mg kg?1 Cd; 10.7 to 24.7?mg kg?1 Pb, 125 to 466?mg kg?1 Cr; 3.1.10 to 14.9?mg kg?1 Cu; 4.7 to 14.3?mg kg?1 Co; 61.1 to 115?mg kg?1 Ni; 106 to 183?mg kg?1 Mn; 52.0 to 170?mg kg?1 Zn and 5 469 to 20 639?mg kg?1 Fe. In general, the metal concentrations were higher in the dry season than the wet season, except for Cr. The concentrations of Cd, Cr, Ni and Zn were above their regulatory control limits in sediment as specified by the Nigerian Regulatory Authority and Cd was identified as the main ecological risk factor. The enrichment factors for the studied metals followed the order: Cd > Cr > Ni > Zn > Pb > Co > Mn > Cu. The average multiple pollution index values indicated that these sediments were severely polluted with significant inputs from Cd, Ni and Cr.  相似文献   

20.
Heavy metal contamination of agricultural soils resulting from rapid industrialization and urbanization is of great concern because of potential health risk due to dietary intake of contaminated vegetables. The present study aims to evaluate the status of heavy metals contamination of agricultural soils and food crops around an urban-industrial region in India. Transfer factor values of Cu, Cr, Pb, Cd, Zn, and Ni from soil to vegetable was estimated. The mean heavy metal concentrations (mg/kg) in agricultural soils (Cu: 17.8, Cr: 27.3, Pb: 29.8, Cd: 0.43, Zn: 87, Mn: 306.6, Fe: 16984, and Ni: 53.8) were within allowable concentrations for Indian agricultural soil. The concentrations of Pb, Cd, Zn, and Ni in crops/vegetables exceeded the World Health Organization/Food and Agriculture Organization safe limits. Relative orders of transfer of metals from soil to edible parts of the crops/vegetables were Cd > Pb > Ni > Zn > Cu > Cr. The enrichment factors of heavy metals in soil indicated minor to moderately severe enrichment for Pb, Cd, and Ni; minor to moderate enrichment for Zn; no enrichment to minor enrichment for Mn; and no enrichment to moderate enrichment for Cu at different sites. Ecological risk index of soil showed considerable contamination in one of the wastewater irrigated sites.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号