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31.
Two iridoid glycosides have been isolated from Viburnum betulifolium. Viburnalloside, the major leaf glycoside, is composed of an iridoid aglucone acylated at C-1 with isovaleric acid and with a di-O-acetyl-β-D-allopyranosyl moiety attached through a glycosidic bond to C-11. Decapetaloside (10-hydroxyiridodial glucoside) has been isolated from the bark. The structure and absolute configuration of viburnalloside have been established by spectroscopic means, and those of decapetaloside by chemical correlation with adoxoside. 相似文献
32.
33.
Armandodoriano Bianco Marcella Guiso Carlo Iavarone Pietro Passacantilli Corrado Trogolo 《Phytochemistry》1981,20(3):465-468
From Verbascum sinuatum, besides aucubin, harpagide, 6-O-β-d-xylopyranosylaucubin and sinuatol (6-O- α-l-rhamnopyranosylaucubin), a new iridoid glycoside, sinuatoside, has been isolated and its structure elucidated as 6-O-(3-O-β-d-xylopyranosyl)α-d-galactopyranosyl aucubin on the basis of spectral data and chemical modifications. For the new disaccharide unit of the latter compound the name sinuatose is proposed. 相似文献
34.
Eight species of Mentzelia (Loasaceae) have been investigated for iridoid glycosides. In addition to the known glucosides deutzioside, decaloside, mongolioside, loganin and sweroside, several novel compounds have been isolated and characterized by chemical and spectroscopic means. 6′-O-Acetyl deutzioside was found in a single species, while the diglycosidic compounds glucosyl-decaloside, allosyl-decaloside and quinovosyl-decaloside were each isolated from one or more species. In addition, a novel compound, epoxydecaloside (= 11-hydroxy-deutzioside), together with glucosyl-epoxydecaloside, allosyl-epoxydecaloside and mentzelosyl-epoxydecaloside are described. The last compound contains a 4-deoxy-α-l-erythro-pentopyranosyl moiety, whose parent sugar, named mentzelose, has not been encountered so far in nature. A non-glycosidic iridoid, mentzetriol, has been characterized solely by spectroscopic means and a structure is proposed. The secoiridoid secoxyloganin has been found for the first time in a plant source, and the coumarin glucoside scopolin has been isolated from two species of Mentzelia. 13C and 1H NMR spectra of several iridoid compounds are presented. The biosynthesis of the compounds is considered and the systematic position of Loasaceae discussed concluding in a possible derivation from Cornalean ancestors. 相似文献
35.
Lucjan Śawia̧tek Daniel Lehmann Ratan K. Chaudhuri Otto Sticher 《Phytochemistry》1981,20(8):2023-2024
The 13C NMR and 360 MHz 1H NMR signals of melittoside and its acetate have been assigned. 相似文献
36.
栀子兰色素可能为栀子粉末外用抗炎消肿时的活性物质 总被引:10,自引:0,他引:10
传统中药山栀子中的环烯醚萜成分及尼平(genipin)与甘氨酸反应可形成兰色素,初步药理实验显示,该兰色色素对小鼠具有抗炎和镇痛作用,推测栀子兰色素可能为民间将栀子粉末外用抗炎消肿时的活性物质。 相似文献
37.
Systematic Separation and Purification of Iridoid Glycosides and Crocetin Derivatives from Gardenia jasminoides Ellis by High‐speed Counter‐current Chromatography 下载免费PDF全文
38.
Abstract. 1. The effect of increasing concentrations of an iridoid glycoside, catalposide, was tested on a generalist and an adapted specialist lepidopteran, using artificial diets.
2. Two strains of the gypsy moth, Lymantria dispar (L.) (Lymantriidae), were tested. Larvae of a wild strain showed a negative dose-dependent response to increasing concentrations of catalposide (up to 7.2% dry weight), while a laboratory strain showed no such pattern. Choice tests using the laboratory strain showed that these larvae often preferred diets relatively low in catalposide over those with higher concentrations.
3. In contrast, larvae of the iridoid glycoside specialist, the buckeye, Junonia coenia Hübner (Nymphalidae), showed a positive dose-dependent response and grew better on diets with higher doses of catalposide.
4. We tested whether the improved growth of J. coenia at higher concentrations of catalposide may have been due to extra glucose yielded by hydrolysis of catalposide. Larvae were fed increasing doses of glucose equivalent to the amount potentially obtained by hydrolysing the quantities of catalposide used in the previous experiment. However, added glucose did not effect growth, suggesting that increased growth at higher catalposide concentrations was due to increased feeding rates. 相似文献
2. Two strains of the gypsy moth, Lymantria dispar (L.) (Lymantriidae), were tested. Larvae of a wild strain showed a negative dose-dependent response to increasing concentrations of catalposide (up to 7.2% dry weight), while a laboratory strain showed no such pattern. Choice tests using the laboratory strain showed that these larvae often preferred diets relatively low in catalposide over those with higher concentrations.
3. In contrast, larvae of the iridoid glycoside specialist, the buckeye, Junonia coenia Hübner (Nymphalidae), showed a positive dose-dependent response and grew better on diets with higher doses of catalposide.
4. We tested whether the improved growth of J. coenia at higher concentrations of catalposide may have been due to extra glucose yielded by hydrolysis of catalposide. Larvae were fed increasing doses of glucose equivalent to the amount potentially obtained by hydrolysing the quantities of catalposide used in the previous experiment. However, added glucose did not effect growth, suggesting that increased growth at higher catalposide concentrations was due to increased feeding rates. 相似文献
39.
Plant defensive compounds can have sometimes severe deleterious effects on both herbivores and their natural enemies. Iridoid glycosides (IGs) are defensive compounds that are well established as deterrent to several generalist herbivores and generalist predators. Trichoplusia ni Hübner (Lepidoptera: Noctuidae) is exceptional among generalist herbivores for its ability to tolerate and thrive when feeding upon IG‐producing plant species; however, it is not known whether the compounds themselves have a harmful effect on T. ni and whether the effects in turn affect its oligophagous endoparasitoid Copidosoma floridanum Ashmead (Hymenoptera: Encyrtidae). To examine these effects, a semi‐purified extract of the IG‐containing plant Plantago lanceolata L. (Plantaginaceae), containing the IGs aucubin and catalpol, was added to artificial diets at 0, 1, 5, or 10% diet dry weight. These diets were fed to both C. floridanum‐parasitized and unparasitized T. ni. Diets higher in IGs tended to be more toxic to both parasitized and unparasitized larvae: host larvae that did survive were slightly smaller and took longer to develop on higher IG diets and total clutch size and survival of the parasitoid C. floridanum were greatly reduced as the host's dietary intake of IGs increased. Only small amounts of aucubin were detected inside the T. ni hemocoel, suggesting that the negative effect of these compounds on C. floridanum is due to nutritional quality of the host being reduced rather than direct toxic effects of the compounds. 相似文献
40.
采用硅胶柱色谱和半制备高效液相色谱等从紫丁香花蕾乙酸乙酯溶液中分离得到8个单体化合物,经理化性质和波谱方法分别鉴定为:丁香苦素B(1)、齐墩果酸(2)、乌苏酸(3)、羽扇豆酸(4)、羽扇豆醇(5)、对羟基苯丙醇(6)、对羟基苯乙醇(7)和β-谷甾醇(8)。其中化合物6首次从该种植物中分离得到,其余均为首次从该植物花蕾中分离得到。 相似文献