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Microwave pretreatment of lignocellulosic material in cholinium ionic liquid for efficient enzymatic saccharification
Institution:1. Institute of Nature and Environmental Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan;2. Division of Material Engineering, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan;3. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodaicho, Nada-ku, Kobe 657-8501, Japan;1. Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA;2. Department of Chemistry, Universitair Centrum Antwerpen, 171 Groenenborglaan, Antwerpen 2020, Belgium;3. Department of Chemistry, Kent State University, Kent, OH 44242, USA;1. CEA, Nuclear Energy Division, RadioChemistry and Process Department, Marcoule Center, 30207 Bagnols-sur-Cèze, France;2. SUBATECH, UMR 6457, Ecole des Mines de Nantes, CNRS/IN2P3, Université de Nantes, 4, Rue Alfred Kastler, La Chantretrie BP 20722, 44307 Nantes cedex 3, France;3. CEMHTI Site Cyclotron, CNRS, 3A rue de la Férollerie, 45071 Orléans Cédex 2, France;4. AREVA NC, BG aval/BO recyclage/RDP, Tour AREVA, 1 place Jean Milier, 92084 Paris La Défense Cedex, France
Abstract:We demonstrated that the enzymatic hydrolysis of cellulose after microwave pretreatment of lignocellulosic material in ionic liquids (ILs) is drastically enhanced compared with that after conventional thermal pretreatment in ILs. Three types of cholinium ILs, choline formate (ChFor), choline acetate (ChOAc), and choline propionate (ChPro), were examined. The cellulose saccharification percentage was approximately 20% for kenaf powders pretreated in ChFor, ChOAc, and ChPro by conventional heating at 110 °C for 20 min. In contrast, approximately 60–90% of cellulose was hydrolyzed to glucose after microwave pretreatment in the same ILs at 110 °C for 20 min.
Keywords:Ionic liquid  Microwave  Lignin  Cellulose  Cellulase  Bioconversion
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