城市污泥与稻草堆肥中邻苯二甲酸酯（PAEs）的研究

将广州城市污泥与稻草进行翻堆、接菌-翻堆、连续通气和间歇通气4种方式的堆肥，应用GC／MS技术对堆肥中6种属于USEPA优控污染物的邻苯二甲酸醇化合物(PAEs)进行分析，探讨堆肥产物中PAEs的含量分布以及不同方式堆肥对PAEs的降解效果，结果表明，4种方式堆肥中PAEs总含量(∑PAEs)在9．815～17．832mg·kg^-1之间，依次为翻堆(17．832mg·kg^-1)>接菌-翻堆(13．927mg·kg^-1)>间隙通气(10．765mg·kg^-1)>连续通气(9．815mg·kg^-1)，堆肥中PAEs以邻苯二甲酸正二辛酯(DhOP)为主，占∑PAEs的82．2％～89．696，不同方式堆肥中∑PAEs的降解率为连续通气(45．71％)>间隙通气(40．4696)>接菌-翻堆(22．97％)>翻堆(1．3796)(平均降解率为27．63％)，其中邻苯二甲酸二乙醇(DEP)、邻苯二甲酸正二丁酯(DnBP)和邻苯二甲酸丁基苄基酯(BBP)的降解率分别为95．7696～98．6896、79．5696～99．46％和87．42％～98．42％；但邻苯二甲酸二甲酯(DMP)和邻苯二甲酸正二辛酯的含量反而增加，邻苯二甲酸(2-乙基己基)酯(DEHP)在所有堆肥中均未检出。

PAEs in composts of municipal sludge and rice straw

Four composting treatments for municipal sludge and rice straw were carried out, which included turning composting, inoculation-turning composting, continuous aeration, and intermittent aeration. GC/MS determination of phthalic acid esters (PAEs) in different composted composts showed that the total contents of six PAE compounds (sigma PAEs) ranged from 0.980-17.832 mg.kg-1, decreasing in the order of turning composting (17.832 mg.kg-1) > inoculation-turning composting (13.927 mg.kg-1) > intermittent aeration (10.765 mg.kg-1) > continuous aeration (9.815 mg.kg-1). DnOP was dominated in the composts. The degradation rate of sigma PAEs after composting was 1.37-45.71% (mean 27.63%), and that of diethyl phthalate (DEP), di-n-butyl phthalate (DnBP) and butylbenzyl phthalate (BBP) was 95.76-98.68%, 79.56-99.46% and 87.42-98.42%, respectively. The concentration of di-n-octyl phthalate (DnOP) was increased in the composts. Aeration-composting, and continuous aeration composting in particular, was more efficient than other treatments to degrade PAEs in municipal sludge.