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1.
对重庆独活种植地土壤及植株中重金属Cu、Pb、Cd、Hg和As进行含量检测、分析。结果表明独活种植地土壤及药材中重金属Cd含量超标。不同器官中重金属元素的含量分布规律不一致,Pb与Cd分布为根茎叶,Cu为茎根叶,Hg为茎叶根,As含量为叶根茎。独活根、茎对Cd的富集能力最强,富集系数大于1,其它元素富集系数均小于1。相关分析表明,土壤中Cu与茎、叶中Cu含量存在极显著相关性,茎和叶中Cu含量呈显著负相关,茎和根中Hg含量呈极显著正相关。  相似文献   

2.
珠江三角洲马尾松年轮重金属含量年代变化   总被引:6,自引:0,他引:6  
采用树木年轮化学分析手段,探讨了肇庆鼎湖山(相对清洁区)和南海西樵山(污染区)马尾松(Pinus massonianaL.)不同时期木质部6种重金属(Cu、Zn、Ni、Cd、Cr和Pb)含量的年代变化。结果表明:西樵山马尾松林地表层土壤Cu、Zn、Cd和Pb含量均超过其在广东省表层土壤环境背景值,鼎湖山马尾松林地表层土壤除Cd外其余重金属含量在背景值范围内;鼎湖山和西樵山马尾松木质部中Cu、Zn、Cr和Pb含量均呈现从心材到边材上升的分布格局,反映了珠江三角洲环境中可供植物利用的重金属在过去有了增加。Cu、Zn、Ni,特别是Cr和Pb的最大含量出现在1990年后形成的木质部中,两地环境(土壤和大气)中重金属含量增加是导致马尾松木质部重金属含量上升的主要原因;在相同时期形成的木质部中,西樵山马尾松木质部Cu、Cr和Pb的含量大于鼎湖山,Zn、Ni和Cd含量则小于鼎湖山,这与环境重金属含量差异有关,也与马尾松对不同重金属的富集能力有关。马尾松年轮化学分析的结果能够提供珠三角地区重金属的历史变化信息。  相似文献   

3.
选择乐安河—鄱阳湖湿地典型植物群落,采用重要值方法评价各样点植物群落特征并筛选出典型优势植物,通过室内理化测试分析不同生境中优势植物植株及其根区土壤中重金属Cu、Pb、Cd的含量;采用生物富集系数(BCF)方法评价不同优势植物对重金属Cu、Pb、Cd的富集特性。结果表明:研究区湿地植物以草本为主,在各样点共发现124种物种,包括蕨类植物2科2属2种,种子植物40科97属122种,并从中筛选出羊蹄、红蓼、鼠曲草、紫云英、苎麻等5种富集能力较强的优势植物;植物根区土壤中的Cu、Cd含量均超过土壤环境质量三级标准,而且Cu、Cd的最高含量分别为824.03、5.03 mg·kg-1;不同优势植物对Cu、Pb、Cd等3种重金属元素中的1种或2种表现出较强的富集能力,其中优势物种红蓼对Cu具有较强的富集能力,含Cu量最高为148.80 mg·kg-1,另一种优势物种鼠曲草对三种元素的生物富集系数均较高,且对Cd的最高富集含量为15.17 mg·kg-1,对Cd的生物富集系数最高值为19.14,高于其他植物10倍以上,鼠曲草对重金属Cd具有富集植物的基本特征,且对Cu和Cd具有共富集特征并具有较高的耐性,紫云英、羊蹄等对Cd的富集能力也较强。上述5种优势植物种群对鄱阳湖湿地Cu、Pb、Cd等重金属污染物的生态修复具有一定参考价值,可作为鄱阳湖湿地重金属污染修复植物的选择对象。  相似文献   

4.
通过对贵州木油厂汞矿区4种藓类植物(真藓、卵蒴真藓、羽枝青藓和圆枝粗枝藓)及其生长基质中的Cu、Zn、Ca、Mg、Cd、Pb、Hg、As 8种元素进行测定分析,以揭示藓类植物与生长基质中重金属元素及其污染程度的关系.结果表明:(1)贵州木油厂汞矿区藓类植物生长基质中Cu、Hg和As元素的平均含量分别是相应国标值的1.29倍、300倍和1.69倍,说明该矿区已受到Cu、Hg和As的污染,且Hg污染特别严重.(2)羽枝青藓的As、Zn、Cd和Pb含量均最高,圆枝粗枝藓的Cu、Ca、Mg和Hg含量均最高,对重金属具有较强的耐受性.(3)羽枝青藓和圆枝粗枝藓对Zn均强烈富集,其富集系数分别为6.14和3.364;羽枝青藓、卵蒴真藓和真藓对Pb均强烈富集,其富集系数分别为13.769、9.547和3.004;表明羽枝青藓对Zn和Pb的富集能力最强,可用于土壤Zn和Pb的污染治理.(4)4种藓类植物对Cu 的富集系数为0.915~1.184,卵蒴真藓和圆枝粗枝藓对Hg的富集系数分别为0.542和0.682,圆枝粗枝藓对As的富集系数为0.74,均为同一水平,表明4种藓类植物可指示其生长基质中Cu、Hg和As的含量.(5)元素间的相关分析显示,木油厂汞矿的Cd和As之间呈显著负相关(P<0.05),表明两元素间有拮抗作用.  相似文献   

5.
杨桃对土壤重金属元素的吸收与富集   总被引:4,自引:0,他引:4  
通过对廉江市杨桃(Averrhoa carambola)绿色食品基地不同土质、不同树龄的土壤样品及果实样品重金属元素Cd、Hg、Cu、Pb、As、Cr含量的检测,分析杨桃果实对土壤重金属元素的吸收与富集作用。结果表明:①果园土壤pH≤5.50,为酸性土壤,杨桃果园土壤和鲜果中的重金属含量均符合我国水果绿色食品生产的质量要求;②杨桃对土壤重金属的吸收因土壤质地和重金属元素的种类不同而异;③杨桃对重金属元素的富集,以Cd元素为最强,富集系数高达0.947,各种重金属的富集系数按大小排序为:Cd(0.947)〉Hg(0.098)〉Cu(0.023)〉Pb(0.003)〉As(0.001):Cr(0.001)。  相似文献   

6.
对内蒙古西部公路绿化植物油松(Pinus tabulaeformis)、小叶杨(Populus simonii)及其根际土壤中重金属元素(Cd、Hg、Pb、Cu、Zn、Ni、Cr)和类金属元素(As和Se)含量以及根际土壤重金属(Cu、Zn、Pb、Ni和Cr)形态、土壤pH值进行了测定。对比分析了公路沿线不同绿化植物及其不同器官对重金属元素的吸收与积累特征。结果表明:绿化植物根际土壤对重金属元素的吸附及污染程度以Cd为最高。随原子序数的递增,小叶杨和油松两种植物的根部和茎叶两种营养器官中重金属的含量均表现出“N”字形变动趋势。而且重金属元素在不同植物不同器官中的含量具有Zn〉Cu〉Ni,Cr,As,Pb〉Cd〉Hg的基本规律。小叶杨茎叶对重金属元素Cr、Ni和Pb的富集能力较根部为强,油松茎叶对重金属元素Cr、Ni、Cu和Pb的富集能力较根部为强。绿化植物根际土壤重金属元素有效态占总量百分比的大小序列为Zn〉Pb〉Ni、Cr〉Cu,与重金属元素在不同植物不同器官中的含量大小序列Zn〉Cu〉Ni、Cr、As、Pb〉Cd〉Hg并非趋于一致。公路绿化植物对根际土壤中重金属元素的吸收和积累与重金属元素有效态所占的比例有关。  相似文献   

7.
广东大中型水库底泥重金属含量特征及潜在生态风险评价   总被引:18,自引:1,他引:17  
广东省45宗大中型水库底泥重金属含量分析评价结果表明:除Cr外,广东省大中型水库底泥中Cu、Zn、Pb和Cd含量均高于广东省土壤重金属含量背景值.广东省四大地理区域中,粤北地区大中型水库底泥Cu、Zn、Pb和Cd平均含量均为最高,分别为89.71、321.21、154.95mg/kg和1.46mg/kg;其次是粤东和粤中地区;粤西大中型水库底泥Cu、Zn、Pb和Cd平均含量均为最低,但Cr平均含量居四大区域之首,为130.81mg/kg.粤东和粤北大中型水库底泥重金属富集系数以Cd最高;粤中和粤西大中型水库底泥重金属富集系数则以Cu最大.总体而言,粤北大中型水库底泥重金属具有很强的潜在生态风险,粤东和粤中大中型水库底泥重金属潜在生态风险程度为中等;粤西大中型水库底泥重金属属于轻微生态风险程度.结果说明,广东省大部分地区大中型水库底泥的重金属潜在生态风险主要是由于底泥中Cd的潜在生态风险系数过高所造成.人为生产活动,特别是矿产开采造成的污染是广东省大中型水库底泥重金属潜在生态风险等级提高的主要原因.  相似文献   

8.
海口城市土壤重金属污染特征与生态风险评估   总被引:5,自引:0,他引:5  
对海口城市土壤重金属含量、空间分布特征与赋存形态进行了研究,并评估了其生态风险。结果表明,海口城市土壤重金属Hg、As、Cd、Cu、Cr、Ni、Pb、Zn的平均含量分别为0.073、3.82、0.25、26.7、92.4、52.5、29.1和84.1 mg·kg-1。与海口土壤背景值相比,海口城市土壤明显富集重金属Hg、As、Cd、Cu、Cr、Ni、Pb和Zn,受到一定程度重金属污染。Cr、Ni、Cu、Cd和Zn元素主要在郊区富集,Pb主要在路边绿化带中富集,Hg主要在生活区富集。海口城市土壤中Zn、As、Cr、Cu和Ni以残渣态为主,Hg主要以强有机态和残渣态存在,Pb主要以铁锰氧化态和残渣态存在,而Cd则主要以生物可利用态为主。生态风险评价结果显示,海口城市土壤重金属综合生态风险属于微弱水平,但Cd和Hg污染应引起重视。  相似文献   

9.
以安顺市至龙天村部分路段位置为基准,选取不同坡度采集距路侧不同距离、高度的油菜及表层土壤样品,测试了各样品中Cu、Pb、Cd、Cr、Zn、Ni、Hg、As元素含量,分析了路侧油菜与土壤中重金属的可能来源、分布规律及表层土壤组成的差异。结果表明:道路截面灰尘有机质含量较高;油菜土壤质地粗细不一,侵入类型以砾石、生活垃圾为主;表层土Cd的Igeo值最高为6.94,属极重污染,Cr、Pb属轻污染;油菜重金属Cd、Cr主要来源地质背景,Pb、Zn、Ni主要受非点源污染源路线影响,Hg、As、Cu与地质背景和人为活动有关;油菜组织重金属含量最大值主要集中在路侧10m内,叶、茎、根中Cr、Cd超标极其严重,分别为:14.49、12.96、15.54倍,35.13、9.54、19.72倍;5m处油菜叶、茎、根对As、Hg、Cr、Pb、Zn、Ni、Cu的富集能力远高于10 m、30 m处。  相似文献   

10.
四川甘洛铅锌矿区优势植物的重金属含量   总被引:17,自引:1,他引:16  
刘月莉  伍钧  唐亚  杨刚  祝亮 《生态学报》2009,29(4):2020-2026
通过野外调查采样,分析了四川凉山州甘洛县铅锌矿区土壤的重金属含量,以及矿区生长的13种优势植物对Pb、Zn、Cd、Cr、Cu的吸收与富集能力及其富集特性.结果表明,矿区土壤受Pb、Zn、Cd 3种重金属污染严重,13种植物体内的Pb含量均高于普通植物10倍以上,具有修复矿区土壤铅污染的潜力,其中植物1的转运系数和富集系数都大于1,满足Pb超富集植物的基本特征.Zn在凤尾蕨、细风轮菜、大火草、蔗茅、小飞蓬和牛茄子中含量较高.小飞蓬和紫茎泽兰的Cd含量较一般植物高出17~61倍,其中,紫茎泽兰的转运系数与富集系数均大于1,其对Cd的吸收特性值得进一步研究.  相似文献   

11.
朱立安  曾清苹  柳勇  柯欢  程炯  张会化  李俊杰 《生态学报》2020,40(13):4659-4669
富集重金属的枯落物分解可能提高重金属暴露率,增加人体接触健康风险。为了解南方城市土壤重金属在森林生态系统中的分布及流转情况,通过调查研究了佛山市8个典型森林群落土壤及枯落物重金属含量,分析了各森林群落枯落物对不同重金属的富集效应及重金属随枯落物回归土壤流通量。结果表明:1)城市森林各土壤重金属含量在不同典型群落间差异显著(P<0.05),差异最大为Pb、Cr、Zn,As、Cu、Ni次之,Hg、Cd最小;土层深度(0-20,20-40,40-60 cm)对重金属含量影响显著(P<0.05),差异最大为Cd、Hg,其次为As、Cu,最小为Zn、Ni、Pb、Cr。整体上,Cd、Hg、As、Pb、Zn在0-20 cm最高,表层富集特征明显,Cr和Ni在40-60 cm最高。2)8个森林群落中阴香-白楸-醉香含笑群落(CMMC)枯落物对8种重金属的综合富集系数(TBCF,66.76)最高,其中以Cd的富集效果最突出,富集系数为44.45,且对Pb、Cu、Zn也相对富集;最低的为黧蒴锥-香椿-樟树群落(CTCC),综合富集系数(TBCF)为8.09,仅对Cd、Cr、Cu相对富集,对其余重金属富集效应不明显。3)相关分析显示,群落重金属枯落物流通量与0-60 cm土壤重金属平均含量(Cr和Ni除外)无显著相关性。本研究对城市森林建设管理及筛选重金属富集植物及群落具有较强理论及实践意义。  相似文献   

12.
桂林市龙胜县作为罗汉果的三大主产区之一,种植区土壤重金属含量及罗汉果质量影响到该区罗汉果产业的健康发展。为探索龙胜县丘陵山区典型贫困村罗汉果园的安全性,该文研究了宝赠村典型罗汉果园土壤及罗汉果果实中砷、铜、锌、铅、镉、铬、汞7种重金属含量,并采用Hankanson指数法分析了其潜在生态风险。结果表明:(1)龙胜丘陵山区罗汉果园土壤(0~10 cm,10~20 cm)重金属含量均达到国家农业用地土壤筛选值标准(GB15618-2018),其中0~10 cm土壤中砷、铜、锌、铅、镉、铬、汞的含量分别为3.67、18.00、58.39、17.01、0.10、28.57、0.08 mg·kg-1,10~20 cm土壤中砷、铜、锌、铅、镉、铬、汞的含量分别为1.93、12.56、21.47、10.51、0.04、17.09、0.02 mg·kg-1。(2)在0~10 cm和10~20 cm土层中,重金属的生态风险状况总体上处于轻微生态风险等级,综合生态风险指数分别为105.29和38.96;0~10 cm土层不同重金属潜在的生态风险顺序为汞>镉>铅>铜>砷>锌>铬,汞、镉的生态风险分别为50.16、42.05,在总重金属风险中贡献率分别占所有重金属的47.6%和39.9%,已达中等生态风险等级;在10~20 cm土层中,7种重金属的生态风险大小关系为镉>汞>铜>铅>砷>铬>锌。(3)研究区罗汉果果实中砷、铜、锌、铅、镉、铬、汞的含量分别为0.00024、0.273、1.10、0.0016、0.00013、0.00013、0.00012 mg·kg-1,其生态风险状况均处于轻微风险等级,7种重金属的生态风险顺序为汞>铜>镉>锌>铅>砷>铬,综合生态风险指数为0.21193,几乎不存在生态风险。因此,在龙胜县丘陵山区典型贫困村——乐江镇宝赠村推广种植的罗汉果达到了安全质量标准。  相似文献   

13.
Irrigation with untreated wastewater from several industrial, commercial, and domestic discharges for decades caused accumulation of various heavy metals and metalloids in soils along the Akaki River in Ethiopia. Assessment of environmental threats and the potential phytoremediation of the soils require understanding of the toxic elements’ uptake and distribution in plant parts. Hence, a greenhouse study was performed to examine the phytoavailability and distribution of Cr, Ni, Co, Cu, Zn, Cd, Pb, Hg, Se, V, and As in forage grasses: Oat (Avena sativa), Rhodes grass (Chloris gayana), Setaria (Setaria sphacelata), and the legumes Alfalfa (Medicago sativa) and Desmodium (Desmodium unicinatum). The average contents of Cr, Ni, Co, Cu, Zn, Pb, Hg, Se, and V in the plants were generally higher than the background levels for forage grasses/legumes, and some of these elements were in the phytotoxic range. Root bioconcentration factor (BCF = root to soil concentration ratio) > 1 was observed for Cu (Oat, Rhodes, Desmodium, and Setaria: Fluvisol), Zn (Setaria: Fluvisol), Cd (Rhodes: Fluvisol; Setaria from both soils) and Hg (Oat and Alfalfa: Fluvisol). Alfalfa and Desmodium displayed translocation factor > 1 (TF = shoot to root concentration ratio) for most heavy metals. Most heavy metals/metalloids may pose a health threat to humans and stock via introduction to the food chain. The plant factors (species and plant part), soil factors (soil type, soil fractions, pH, and CEC), and their interactions significantly (p < 0.05) influenced plant heavy metal and metalloid levels. However, the role of plant part and species emerged as the most important on heavy metal uptake, translocation, sequestration, and ultimately transfer to the food chain. Accordingly, the uptake and distribution of heavy metals/metalloids in the plants reflect the potential environmental and health hazards attributable to the use of fodder grasses, legumes, and cultivation of vegetables in soils with polymetallic and metalloid contamination.  相似文献   

14.
The bioaccumulation and rhizofiltration potential of P. stratiotes for heavy metals were investigated to mitigate water pollution in the Egyptian wetlands. Plant and water samples were collected monthly through nine quadrats equally distributed along three sites at Al-Sero drain in Giza Province. The annual mean of the shoot biomass was 10 times that of the root. The concentrations of shoot heavy metals fell in the order: Fe < Mn < Cr < Pb < Cu < Zn < Ni < Co < Cd, while that of the roots were: Fe < Mn < Cr < Pb < Zn < Ni < Co < Cu < Cd. The bio-concentration factor (BCF) of most investigated heavy metals, except Cr and Pb, was greater than 1000, while the translocation factor (TF) of most investigated metals, except Pb and Cu, did not exceed one. The rhizofiltration potential (RP) of heavy metals was higher than 1000 for Fe, and 100 for Cr, Pb and Cu. Significant positive correlations between Fe and Cu in water with those in plant roots and leaves, respectively were recorded, which, in addition to the high BCF and RP, indicate the potential use of P. stratiotes in mitigating these toxic metals.  相似文献   

15.
Hazard evaluation of different heavy metal exposure on the crops cultivated around two abandoned metal mine sites was conducted. Bioconcentration Factor (BCF) of nine heavy metals including Cu, Cd, Hg, As, Cr, Zn, Pb, Mn, and Al in the samples of brown rice cultivated at exposed soil were measured. Soil-plant BCF was measured and compared with Korean and US EPA standards. BCF values of analyzed heavy metals except Hg and As were below the limits. BCF of Hg was over 5 times higher than the standard limit. Excess cancer risk (ECR) and hazard quotient (HQ) values of As was higher than the limit and suggested to have carcinogenic as well as non-carcinogenic threat to the public exposed to the sites. The data presented could be utilized in prioritizing abandoned metal mine sites for health effect survey.  相似文献   

16.
This work investigates the phytoremediation potential of Aeluropus lagopoides and Cyperus conglomeratus, growing indigenously in the vicinity of an artificial lake of reclaimed water in Tabuk, Saudi Arabia . The sampling sites were located at different distances from the wastewater treatment plants. Trace metal contents were higher in roots than shoots in both these plants. Soil urease activity in rhizophere increased linearly along the sampling sites, however, soil alkaline phosphatase and β-glucosidase activities were higher at site 2 but at site 3, the activities of both these soil enzymes reduced. Significant correlations were observed between soil urease activity and the bioconcentration factor (BCF) of Cd, Cu, Pb, and As in A. lagopoides and translocation factor (TF) for all metals in both these plants. Soil β-glucosidase activity was negatively correlated with the TF of Cd, Cu, Pb, and As in A. lagopoides and positively in C. conglomeratus, respectively. Higher BCF of Cd, Cu and Pb than C. conglomeratus and suitable for phytostabilization, however at site 3, C. conglomeratus showed better phytostabilization efficiency for As, as the BCF of As was higher than the A. lagopoides. On the basis of metal accumulation efficiency and rhizospheric soil urease and β-glucosidase activities, A. lagopoides species proved to be a better option for application in phytostabilization strategy than C. conglomeratus plants in the area surrounding the artificial lake of reclaimed water in Tabuk, Saudi Arabia.  相似文献   

17.
The aim of the study was to determine tolerance of plant growth promoting rhizobacteria (PGPR) in different concentrations of Cu, Cr, Co, Cd, Ni, Mn, and Pb and to evaluate the PGPR-modulated bioavailability of different heavy metals in the rhizosphere soil and wheat tissues, grown in saline sodic soil. Bacillus cereus and Pseudomonas moraviensis were isolated from Cenchrus ciliaris L. growing in the Khewra salt range. Seven-day-old cultures of PGPR were applied on wheat as single inoculum, co-inoculation and carrier-based biofertilizer (using maize straw and sugarcane husk as carrier). At 100 ppm of Cr and Cu, the survival rates of rhizobacteria were decreased by 40%. Single inoculation of PGPR decreased 50% of Co, Ni, Cr and Mn concentrations in the rhizosphere soil. Co-inoculation of PGPR and biofertilizer treatment further augmented the decreases by 15% in Co, Ni, Cr and Mn over single inoculation except Pb and Co where decreases were 40% and 77%, respectively. The maximum decrease in biological concentration factor (BCF) was observed for Cd, Co, Cr, and Mn. P. moraviensis inoculation decreases the biological accumulation coefficient (BAC) as well as translocation factor (TF) for Cd, Cr, Cu Mn, and Ni. The PGPR inoculation minimized the deleterious effects of heavy metals, and the addition of carriers further assisted the PGPR.  相似文献   

18.
Pinus banksiana andPicea glauca inoculated or not with the ectomycorrhizal fungusSuillus luteus were grown in a sandy loam soil containing a range of Cd, Cu, Ni, Pb and Zn concentrations. Ectomycorrhizal colonization rates were significantly reduced on Pinus and Picea seedlings by the heavy metals, particularly Cd and Ni. Needle tissue metal concentrations were lower in ectomycorrhizal seedlings at low soil metal concentrations. However, at higher soil concentrations, heavy metal concentrations of needle tissue were similar in ectomycorrhizal and nonmycorrhizal plants. The growth of nonmycorrhizal seedlings exposed to heavy metals was reduced compared to those inoculated withSuillus luteus. Apparently ectomycorrhizal colonization can protect Pinus and Picea seedlings from heavy metal toxicity at low or intermediate soil concentrations of Cd, Cu, Ni, Pb and Zn.  相似文献   

19.
为探讨油茶(Camellia oleifera)产地土壤和油茶果实中金属元素分布和富集特征,在油茶果实成熟期,对浙江5个油茶产地土壤及油茶果实中金属元素进行污染分析和富集能力评价。结果表明,浙江油茶产地土壤中Pb、Cr、Cd、As、Hg、Ni、Cu和Zn含量低于农用地土壤污染风险筛选值,综合污染等级为安全。个别产区常山县土壤中As、Ni、Cu和江山县土壤中Pb、Cr、Fe含量显著高于其他产地;常山和建德土壤中Cd单因子污染指数分别为0.93和0.81,处于污染警戒线。Cr、Ni、Cu、Zn主要分布在油茶籽中,Hg主要分布在壳中,Pb、Cd、As、Fe和Mn主要分布在青皮中。油茶籽中Cu、Fe、Mn的富集系数大于0.4,吸收能力强,Ni、Zn的富集系数小于0.4,具有一定吸收能力,Pb、Cr、Cd、As和Hg的富集系数小于0.1,吸收能力低;壳中Cu、Mn的富集系数大于0.4,吸收能力强,Fe的富集系数小于0.4,具有一定吸收能力,Pb、Cr、Cd、As、Hg、Ni、Zn的富集系数小于0.1,吸收能力低;青皮中Cu、Fe、Mn的富集系数大于0.4,吸收能力强,Pb、Cr、Cd、As、Hg、Ni、Zn的富集系数小于0.1,吸收能力低。浙江油茶主产区土壤质量安全,适合油茶种植。油茶果实对Cu、Fe、Mn有一定富集能力,对Pb、Cr、Cd、As和Hg无富集能力。  相似文献   

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