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Single flexible nanofiber to achieve simultaneous photoluminescence–electrical conductivity bifunctionality
Authors:Shujuan Sheng  Qianli Ma  Xiangting Dong  Nan Lv  Jinxian Wang  Wensheng Yu  Guixia Liu
Abstract:In order to develop new‐type multifunctional composite nanofibers, Eu(BA)3phen/PANI/PVP bifunctional composite nanofibers with simultaneous photoluminescence and electrical conductivity have been successfully fabricated via electrospinning technology. Polyvinyl pyrrolidone (PVP) is used as a matrix to construct composite nanofibers containing different amounts of Eu(BA)3phen and polyaniline (PANI). X‐Ray diffractometry (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), fluorescence spectroscopy and a Hall effect measurement system are used to characterize the morphology and properties of the composite nanofibers. The results indicate that the bifunctional composite nanofibers simultaneously possess excellent photoluminescence and electrical conductivity. Fluorescence emission peaks of Eu3+ ions are observed in the Eu(BA)3phen/PANI/PVP photoluminescence–electrical conductivity bifunctional composite nanofibers. The electrical conductivity reaches up to the order of 10−3 S/cm. The luminescent intensity and electrical conductivity of the composite nanofibers can be tuned by adjusting the amounts of Eu(BA)3phen and PANI. The obtained photoluminescence–electrical conductivity bifunctional composite nanofibers are expected to possess many potential applications in areas such as microwave absorption, molecular electronics, biomedicine and future nanomechanics. More importantly, the design concept and construction technique are of universal significance to fabricate other bifunctional one‐dimensional naonomaterials. Copyright © 2014 John Wiley & Sons, Ltd.
Keywords:luminescence  electrical conductivity  polyaniline  electrospinning  nanofibers
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