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Three series of high molecular weight alkanoates found in Amazonian plants
Authors:Pereira Alberto S  Siqueira Denilson S  Elias Vladimir O  Simoneit Bernd R T  Cabral José A  Aquino Neto Francisco R
Institution:LADETEC, Instituto de Qui;mica, Universidade Federal do Rio de Janeiro, Ilha do Fund?o, Centro de Tecnologia, Bloco A, Sala 607, 21949-900, Brazil.
Abstract:Electron impact mass spectra were measured by high temperature high resolution gas chromatography-mass spectrometry (HT-HRGC-MS) for three homologous series of high molecular weight compounds present in the Amazonian plants Marupá (Simaruba amara) and Brazil nut (Bertholettia excelsa). Based on their mass spectra, the compounds were identified as three wax ester series of alpha-tocopherol (vitamin E), beta-tocopherol and phytol (2,6,10,14-tetramethylhexadec-14-en-16-ol). The interpretations are supported by high resolution mass spectrometry and GC retention indices of authentic standards.
Keywords:Simaruba amara  Wax esters  Tocopheryl alkanoates  Phytyl alkanoates  Quassia  Bertholettia excelsa  Lecithidaceae
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