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Biosynthesis of the sesquiterpene hodgsonox from the New Zealand liverwort Lepidolaena hodgsoniae |
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| Authors: | Barlow Anna J Lorimer Stephen D Morgan Ed R Weavers Rex T |
| Affiliation: | Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand. |
| Abstract: | The incorporation of [1-13C] labelled glucose into hodgsonox, a sesquiterpene epoxide with a unique, doubly allylic ether functionality has been studied in axenic cultures of the liverwort Lepidolaena hodgsoniae. Quantitative 13C NMR spectroscopic analysis showed that the isoprene units are derived exclusively from the methylerythritol phosphate pathway. |
| Keywords: | Lepidolaena hodgsoniae Lepidolaenaceae Biosynthesis Isopentenyl diphosphate Methylerythritol phosphate pathway Sesquiterpenoid Isoprenoids 13C-labelling Quantitative 13C NMR spectroscopy Liverwort tissue culture |
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