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Polymerization of 4-Nitrophenyl Acrylate under Microwave Heating Conditions |
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| Authors: | Dikusar M A Kubrakova I V Chinarev A A Bovin N V |
| Institution: | (1) Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, ul. Miklukho-Maklaya 16/10, GSP Moscow, 117997, Russia;(2) Vernadskii Institute of Geochemistry and Analytical Chemistry, ul. Kosygina 19, Moscow, 117975, Russia |
| Abstract: | The 2,2"-azodiisobutyronitrile-induced radical polymerization in solution of 4-nitrophenyl acrylate was performed under microwave heating at a frequency of 2.45 GHz. This approach allows the control of the molecular weight of poly(4-nitrophenyl acrylate) used in the synthesis of multivalent glycoconjugates. It was found that the polymerization of 4-nitrophenyl acrylate under microwave irradiation results in products with a narrower molecular mass distribution than at conventional heating. |
| Keywords: | microwave heating multivalent glycoconjugates poly(4-nitrophenyl acrylate) radical polymerization |
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