Low-pressure microwave-induced helium plasma emission spectrometry: Vaporization characteristics of metal chlorides,nitrates, and sulfates |
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Authors: | Masaaki Yanagisawa Hiroshi Kawaguchi Bert L Vallee |
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Institution: | 1. Biophysics Research Laboratory, Department of Biological Chemistry, Harvard Medical School, Boston, Massachusetts USA;2. Division of Medical Biology, Peter Bent Brigham Hospital, Boston, Massachusetts USA |
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Abstract: | A low-pressure microwave-induced helium plasma serves as an excitation source for metal chlorides, nitrates, and sulfates vaporized from a filament, resulting in fractional vaporization and differential sensitivities of detection of the elements depending on the vapor pressures of their salts. The shapes of the single emission peaks, which are simple in the presence of potassium chloride, become complex and may double in number. |
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