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Infrared and raman spectra of specifically deuterated 1,2-dipalmitoyl-sn-glycero-3-phosphocholines
Authors:S Sunder  DG Cameron  HL Casal  Y Boulanger  HH Mantsch
Institution:1. Whiteshell Nuclear Research Establishment, Atomic Energy of Canada Limited, Pinawa, Manitoba R0E 1L0 Canada;2. National Research Council of Canada, Ottawa, Ontario K1A 0R6 Canada
Abstract:Deuterated methylene groups have been introduced synthetically in selected positions of the sn-2 palmitoyl chain of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and deuterated methyl groups in the sn-1 and sn-2 palmitoyl chains as well as in the sn-3 phosphocholine group.The vibrational spectra of seven such deuterium labelled derivatives of the title compound have been studied as the assignment of the C–D stretching vibrations is discussed.
Keywords:DPPC  TLC  thin-layer chromatography
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