Novel chiral sulfur-containing ferrocenyl ligands for palladium-catalyzed asymmetric allylic substitution |
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| Authors: | Nakamura Shuichi Fukuzumi Takeo Toru Takeshi |
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| Affiliation: | Department of Applied Chemistry, Nagoya Institute of Technology, Nagoya, Japan. |
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| Abstract: | New chiral ferrocenyl ligands having chiral sulfinyl and phosphinyl groups were prepared. The palladium-catalyzed allylic substitution reaction using these chiral ligands showed good enantioselectivity. The mechanism for the asymmetric reaction is proposed on the basis of the stereochemical outcome. |
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| Keywords: | allylic substitution ferrocene enantioselective reaction sulfoxide P,S‐bidentate ligands |
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