|
|||||
|
|
Synthesis of a protected trihydroxyindolizidine 3-carboxylate via a hetero-Diels–Alder addition of ethyl 2-nitrosoacrylate to a d-ribose-derived exo-glycal |
|
| Authors: | Zoe S Massen Evdoxia Coutouli-Argyropoulou Vassiliki C Sarli John K Gallos |
| Institution: | Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece |
| Abstract: | A protected trihydroxyindolizidine 3-carboxylate was prepared by a 6-endo epoxide cleavage, which in turn was intermediately formed from the hetero-Diels–Alder adduct of ethyl 2-nitrosoacrylate to a d-ribose-derived exo-glycal. |
| Keywords: | Polyhydroxylated indolizidine alkaloids Ethyl bromopyruvate Ethyl 2-nitrosoacrylate Hetero-Diels&ndash Alder cycloaddition exo-Glycals Catalytic hydrogenation |
| 本文献已被 ScienceDirect 等数据库收录！ | |