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Luminescence properties of Tm3+ ions single‐doped YF3 materials in an unconventional excitation region
Authors:Yuan Chen  Qing Liu  Han Lin  Xiaohong Yan
Affiliation:1. College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing, P. R. China;2. Key Laboratory of Radio Frequency and Micro‐Nano Electronics of Jiangsu Province, Nanjing, P. R. China;3. College of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing, P. R. China;4. School of Material Science and Engineering, Jiangsu University, Zhenjiang, P. R. China
Abstract:According to the spectral distribution of solar radiation at the earth's surface, under the excitation region of 1150 to 1350 nm, the up‐conversion luminescence of Tm3+ ions was investigated. The emission bands were matched well with the spectral response region of silicon solar cells, achieved by Tm3+ ions single‐doped yttrium fluoride (YF3) phosphor, which was different from the conventional Tm3+/Yb3+ ion couple co‐doped materials. Additionally, the similar emission bands of Tm3+ ions were achieved under excitation in the ultraviolet region. It is expected that via up‐conversion and down‐conversion routes, Tm3+‐sensitized materials could convert photons to the desired wavelengths in order to reduce the energy loss of silicon solar cells, thereby enhancing the photovoltaic efficiency.
Keywords:down‐conversion  photoluminescence  solar energy  Tm3+‐ions single‐doped  up‐conversion
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