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Intense green light emission in Sr2ZnGe2O7:Mn2+ phosphors by the design of high symmetry melilite structure
Authors:Yongzheng Fang  Yuhang Li  Chengze Wang  Wenxiang Yin  Tongna Shi  Ganghua Zhang  Guoying Zhao  Xiaoping Zhou  Jiexiang Yang  Dehua Wu  Langping Dong  Jingshan Hou
Institution:1. School of Materials and Science and Engineering, Shanghai Institute of Technology, Shanghai, China;2. National Experimental Teaching Demonstration Center for Materials Science and Engineering, Donghua University, Shanghai, China;3. Changzhou Xingyu Automotive Lighting System Co, Ltd, Changzhou, China;4. Shanghai Sarui Optoelectronic Technology Co., Ltd, Shanghai, China

Shaoxing Shangrui Optoelectronic Technology Co., Ltd, Shaoxing, China;5. Shandong Huaguang Optoelectronics Co., Ltd, Jinan, China

Abstract:A green phosphor Sr2ZnGe2O7:Mn2+ with a melilite structure was prepared using a high-temperature solid-state reaction. When the 535 nm emission was monitored, the excitation spectrum of the Sr2ZnGe2O7:Mn2+ was found to contain two excitation bands in the ultraviolet (UV) region. When excited by UV light, the sample shows bright green emission at 535 nm, which corresponds to the distinctive transition of Mn2+ (4T16A1). Moreover, the quantum efficiency of Sr2ZnGe2O7:Mn2+ could reach 67.6%. Finally, a high-performance white-light-emitting diode (WLED) with a low correlated colour temperature of 4632 K and a high colour rendering index (CRI) of 92.3 were packaged by coating commercial blue and red phosphors with an optimized Sr2ZnGe2O7:Mn2+ sample on a 310 nm UV chip. This indicated that Sr2ZnGe2O7:Mn2+ has the potential application as a green component in the WLED lighting field.
Keywords:high colour rendering index  melilite  Mn2+-doped green phosphor  white light
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