Biosynthesis of antifungal isoflavonoids in Lupinus albus. Enzymatic prenylation of genistein and 2'-hydroxygenistein. |
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Authors: | Gudrun Schröder Ulrich Zähringer Werner Heller Jürgen Ebel Hans Grisebach |
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Affiliation: | Lehrstuhl für Biochemie der Pflanzen Institut für Biologie II Universität Freiburg, Schänzlestr. 1 D-7800 Freiburg i.Br., Germany |
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Abstract: | A 45,000g particulate fraction from hypocotyls of Lupinus albus catalyzes the prenylation of genistein 1 and 2′-hydroxygenistein 2 with dimethylallyl pyrophosphate to the antifungal 6-isopentenylgenistein 3 (wighteone) and 6-isopentenyl-2′-hydroxygenistein 4 (luteone), respectively. |
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