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Water-Organic Solvent Two-Phase Systems As Media For Biocatalytic Reactions: The Potential For Shifting Chemical Equilibria Towards Higher Yield Of End Products
Authors:A N Semenov  Yu L Khmelnitski  I V Berezin  K Martinek
Institution:  a All-Union Cardiology Centre, Moscow, USSR b Institute of Biochemistry, USSR Academy of Sciences, Moscow, USSR c Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, Prague, Czechoslovakia
Abstract:This review emphasizes that the yield of the end products of chemical (biocatalytic) reactions in the two-phase system can, in principle, be much higher than in either medium (water or organic solvent) separately. A theoretical analysis of this phenomenon is presented and exemplified by some simple reactions.
Keywords:Enzyme-catalyzed organic synthesis
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