Crystal structure of antimony(II) monothiobenzoate,Sb(PhCOS)3 |
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| Authors: | Rainer Mattes Dieter Rühl |
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| Institution: | Institute of Inorganic Chemistry, Univesity of Muenster, Corrensstrasse 36, 4400 Muenster, F.R.G. |
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| Abstract: | The title compound crystallizes rhombohedrally in the space group R3 with a = 20.453(11) and c = 4.197(1) Å (hexagonal setting). The structure was refined by full matrix lest squares with 585 independent reflections to R equal 0.042 (Rw = 0.040). Antimony, situated on the threefold axis, is pyramidally coordinated at 2.493(3) Å to the sulfur atoms of the three ligands. Secondary bonding occurs at 2.802(8) Å to the oxygen atoms of the asymmetrically chelating ligands. |
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