Synthesis,structure and electrochemistry of (ferrocene-2-propenoato-O,O′)bis[1,2-bis(diphenylphosphino)ethane-P,P′]ruthenium(II) hexafluorophosphate |
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| Affiliation: | 1. Department of Chemistry, St. Francis Xavier University, P.O. Box 5000, Antigonish, Nova Scotia, Canada B2G 2W5;2. Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3;3. Department of Chemistry, University of the Free State, P.O. Box 339, Nelson Mandela Drive, Bloemfontein 9300, South Africa;1. University Politehnica Timisoara, Research Institute for Renewable Energy, 2 Piata Victoriei, 300006 Timisoara, Romania;2. West University of Timisoara, 4 B-dul Vasile Parvan, 300223 Timisoara, Romania;1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan;2. JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan;1. Facultad de Química, Universidad Nacional Autónoma de México (UNAM), Ciudad Universitaria, Coyoacán 04510, México D.F., Mexico;2. Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, C.P. 62209 Cuernavaca, Morelos, Mexico;3. Área académica de Químicas, Universidad Autónoma del Estado de Hidalgo, Unidad Universitaria, Km 4.5 Carretera Pachuca-Tulancingo, C.P. 42184 Pachuca-Hidalgo, Mexico;4. Área de Química Inorgánica-CIESOL, Universidad de Almería, Almería, 04120 Almería, Spain |
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| Abstract: | The complex [Ru(η2-fcpe)(dppe)2](PF6) (1), where fcpe = ferrocene-2-propenoate and dppe = 1,2-bis(diphenylphosphino)ethane, was synthesized via a “dimer disassembly” method and characterized using elemental analysis, IR spectroscopy, 1H and 31P NMR and X-ray crystallography. The redox potentials of the metal centers were assessed using cyclic voltammetry and Osteryoung square-wave voltammetry. No significant metal–metal interactions were found. |
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