Oscillating chemiluminescence systems: state of the art |
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Authors: | Mortaza Iranifam Marcela A Segundo João L M Santos José L F C Lima Mohammad H Sorouraddin |
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Institution: | 1. Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, East Azerbaijan, Iran;2. REQUIMTE, Departamento de Química‐Física, Faculdade de Farmácia, Universidade do Porto, R. Anibal Cunha, 164, Porto, Portugal;3. Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran |
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Abstract: | Oscillating chemiluminescence (CL) was reported for the first time about 30 years ago. Since then several systems based on addition of a chemiluminescent reagent to a known oscillator system or based on the light emitting features of one component of the oscillating system, have been described. This information, scattered in the scientific literature, is compiled in the present paper. Several oscillating CL systems, including those based on Belousov–Zhabotinskii and Orban oscillators, or horseradish peroxidase‐catalyzed reactions, among others, are critically presented. The application of this type of oscillatory systems is also discussed, in analytical chemistry and for educational purposes. Copyright © 2010 John Wiley & Sons, Ltd. |
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Keywords: | oscillating chemiluminescence Belousov– Zhabotinskii system Orban oscillatory systems nonequilibrium chemical systems |
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