Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation |
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| Authors: | Maeda Takeshi Furusho Yoshio Takata Toshikazu |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, Japan. |
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| Abstract: | Poly(binaphthyl salen manganese complex)es 3-Mn were synthesized from a 3,3'-diformylbinaphthol derivative, alpha,omega-diamines, and Mn(OAc)2. Their helical structures were well-supported by their IR, UV, and CD spectra. The catalysis of 3-Mn in an asymmetric epoxidation was investigated. |
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