Liming to remediate Ni contaminated soils with diverse properties and a wide range of Ni concentration |
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Authors: | Grzegorz Siebielec Rufus L Chaney Urszula Kukier |
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Institution: | (1) Institute of Soil Science and Plant Cultivation, Czartoryskich 8, 24-100 Pulawy, Poland;(2) Animal Manure & By-products Laboratory, USDA-ARS, Beltsville, MD 20705, USA;(3) Department of Crop and Environmental Soil Sciences, Virginia Tech, Blacksburg, VA, USA |
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Abstract: | Historic emissions from a Ni refinery at Port Colborne, Ontario, caused Ni contamination of regional soils and raised concerns
about potential Ni phytotoxicity. Previous tests revealed that if these soils were made alkaline and fertilized with Mn and
other common nutrients as needed to maintain fertility of such alkaline soils, full remediation (prevention of Ni phytotoxicity)
would be obtained. This experiment was conducted to test this method of remediation on diverse soils from Port Colborne, and
to evaluate chemical extraction tests which would be predictive of plant uptake and potential for Ni phytotoxicity in Ni-contaminated
soils. Ten soils with varied levels of Ni contamination and varied soil properties were amended with limestone or nitric acid
to raise or lower pH so that a wide pH range could be examined for the soils. For lower Ni organic and mineral soils near
the Ontario remediation limit (200 mg/kg), neither crop suffered Ni phytotoxicity at any pH tested. Only when more highly
contaminated soils were strongly acidic did Ni phytotoxicity occur. Phytotoxic soils were fully remediated by making soils
alkaline even for these Ni-sensitive crop species. Only the most contaminated organic soil remained slightly toxic – but this
soil was remarkably contaminated (over 1.1% of Ni). The Sr nitrate extraction method was much more effective in predicting
plant Ni concentrations than the DTPA method. This test provides an inexpensive soil extraction result highly predictive of
potential for Ni phytotoxicity across soils. |
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Keywords: | Contamination Extraction Liming Nickel Phytotoxicity Remediation |
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