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Sulfur ligands within the cluster formations of copper at its strong'binding sites on the cytoplasmic membrane of Escherichia coli]
Authors:L A Volodina  L M Ba?der  D Sh Burbaev  L A Bliumenfel'd
Institution:Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences, Moscow, Russia.
Abstract:The analysis of the saturation curves of ESR signals revealed a decrease in the relaxation rate of fast-relaxation Cu(I) complexes on the cytoplasmic membrane of E. coli after the interaction of these bacteria with low concentrations of SH-reagents. It was concluded that the observed changes are associated with the reorganization of Cu clusters due to the binding of SH groups incorporated into the clusters N-ethylmaleimide or Ag(I).
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