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New coumarins from the umbels of Seseli sibiricum
Authors:Sunil K. Banerjee  Bishan D. Gupta  Raman Kumar  C.K. Atal
Affiliation:Regional Research Laboratory (C.S.I.R.), Jammu-Tawi, India
Abstract:Three new coumarins, seselinal, sesibiricol and sibirinol, and 12 known coumarins have been isolated from the umbels of Seseli sibiricum. The new coumarins have been characterized as 5, 7-dimethoxy-8-(2-methyl-2-formylpropyl)-2H-1-benzopyran-2-one, 5-(3-methylbut-2-enyloxy)-7-methoxy-8-(2-hydroxy-3-methylbut-3-enyl)-2H-1-benzopyran-2-one and 5,7-dimethoxy-8-(2-hydroxy-3-methylbut-3-enyl)-2H-1-benzopyran-2-one,respectively. The known ones were identified as sesibiricin, isosibiricin, osthol, coumurrayin, sesebrin, sesebrinol, sibiricin, imperatorin, bergapten, xanthotoxin, isopimpinellin and mexoticin.
Keywords:Umbelliferae  umbels  coumarins  2H-1-benzopyran-2-one  seselinal  sesibiricol  sibirinol  isosibiricin  sesibiricin  osthol  coumurrayin  sesebrin  sesebrinol  sibiricin  imperatorin  bergapten  xanthotoxin  isopimpinellin  mexoticin.
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