|
|||||
|
|
Novel 2D supramolecular array based on antibacterial drug norfloxacin |
|
| Authors: | Yu-Cheng Wang Qiong Ye Ren-Gen Xiong Hoong-Kun Fun |
| Affiliation: | a Department of Chemistry, Xuzhou Normal University, Xuzhou 221116, PR China b Coordination Chemistry Institute, The State Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China c X-ray crystallography Unit, School of Physics, 11800, USM, Penang, Malaysia |
| Abstract: | Self-assembly reaction of Cd(ClO4)2 · 6H2O with Norfloxacin (H-Norf) affords a novel 2D rectangular grid framework [Cd(Norf)(ClO4)(H2O)] (1) with strong blue luminescent emission (λem=425 nm), while Norf− acts as a tetradentate bridging linker to connect three Cd centers and ClO4 − completes Cd center octahedron coordination geometry. The compound 1 has crystallographic data of triclinic, space group  , a=9.4577(1) Å, b=9.5012(2) Å, c=12.2805(1) Å, V=3624.4(3) Å3, Z=2. |
| Keywords: | Cadmium Norfloxacin Self-assembly Metal-organic framework Fluorescence |
| 本文献已被 ScienceDirect 等数据库收录！ | |