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Synthesis and structural characterization of a novel diosmium(III) compound: Os2(ap)4Cl2 |
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| Authors: | Tong Ren Damon A. Parrish Jeffrey R. Deschamps Guo-Lin Xu Martin H. Moore Steven K. Pollack A.P. Sattelberger |
| Affiliation: | a Department of Chemistry, University of Miami, 1301 Memorial Drive, Coral Gables, FL 33146, USA b Naval Research Laboratory, Washington, DC 20375, USA c Los Alamos National Laboratory, Los Alamos, NM 87545, USA |
| Abstract: | The reaction between Os2(OAc)4Cl2 and Hap (Hap is 2-anilinopyridine) under prolonged refluxing conditions resulted in a new Os2(III) compound, Os2(ap)4Cl2 (1). The molecular structure of 1 was determined from a single crystal X-ray diffraction study, which revealed an Os-Os bond length of 2.396[1] Å, and a cis-(2,2) arrangement of the ap ligands. Also reported are magnetic, electrochemical and spectroscopic properties of 1. |
| Keywords: | Diosmium(III) 2-Anilinopyridinate Crystal structure |
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