|
|||||
|
|
Bis-axial cyanide coordination induces high nucleophilicity of the in-plane thiolato ligands bound to a Co(III) center: model complexes related to the Co-containing nitrile hydratases |
|
| Authors: | Laurent Heinrich Jacqueline Vaissermann Yun Li |
| Affiliation: | a Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, Université René Descartes, UMR 8601 CNRS, 45 rue des Saints-Pères, F-75270 Paris Cedex 06, France b Laboratoire de Chimie Inorganique et Matériaux Moléculaires, Université Pierre et Marie Curie, ESA 7071, 75252 Paris Cedex 05, France |
| Abstract: | In situ cyanide bis-axial coordination of a square planar complex [CoIIIN2S2]−, containing a di-N-carboxamido and dithiolato tetradentate ligand, generates the highly nucleophilic species [CoIIIN2S2(CN)2]3−. Its di-S-chloromethylation and di-S-oxygenation products were isolated and structurally characterized. |
| Keywords: | Cobalt Nitrile hydratases Carboxamido complexes Oxygenation S-sulfinato ligands Chloromethanesulfido ligands |
| 本文献已被 ScienceDirect 等数据库收录！ | |