Aminopyrimidines and Derivatives. 19 1. Reaction of 1, 6-Dihydro-4-Beta; D (2, 3, 4, 6-Tetra-0-Acetyl)Glucopyranosylamino-1-Methyl-Z-Methoxy-6-Oxo Pyrimidine with Choracetyl Chloride |
| |
| Authors: | Manuel Nogueras Luisa Quijano Miguel Melgarejo Adolfo Sqnchez |
| |
| Affiliation: | 1. Depto. Quimica OrgQnica. , Colegio Universitario , 23071, Jaén, Spain;2. Depto. Quimica OrgQnica. , Universidad De Granada , 18071, Granada, Spain |
| |
| Abstract: | Abstract Reaction between 1, 6-dihydro-4-β-D(2, 3, 4, 6-tetra-O-acetyl) glucopyranosylamino-l-methyl-2-methoxy-6-oxo pyrimidine and chloracetyl chloride yields the corresponding 5-α-chloracetyl derivative and 2,6-di oxo-4-β -D (2,3,4,6-tetra-0-acetyl) glucopyranosylamino-l-methyl-1,2,3,6 tetrahdro pyrimidine. The first compund has been cyclized to the corresponding 7-β-D-glucopyranosyl-pyrrolo 2, 3-d pyrimidine and the second one to 3-βD-glucopyranosyl-vic-triazolo 4,5-d pyrimidine. |
| |
| Keywords: | |
|
|
