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On the Structure and Reactivity of Y-Nucleoside [Wyosine]
Authors:C. Glemarec  J-C. Wu  H. Bazin  G. Remaud  M. Oivanen  H. Lönnberg
Affiliation:1. Department of Bioorganic Chemistry , Box 581, Biomedical Center , S-751 23, Uppsala, Sweden;2. Dept. of Chemistry &3. Biochemistry , University of Turku , SF-20500, Turku, Finland
Abstract:Abstract

Wyosine-Triacetate 4 has found to undergo electrophilic reactions exclusively at the C-7 position. 15N-NMR of 4, shows that the primary site of protonation is N-5 suggesting that the “right” imidazole ring is more aromatic that the “left” imidazole moiety.
Keywords:
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