Pummerer Rearrangement of Selenium-Containing Uracil Nucleosides |
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Authors: | Kazuhiro Haraguchi Shigeru Saito Hiromichi Tanaka Tadashi Miyasaka |
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Affiliation: | School of Pharmaceutical Sciences, Showa University , Hatanodai 1-5-8, Shinagawa-ku, Tokyo, 142, Japan |
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Abstract: | Abstract Pummerer-type rearrangement of uracil nucleosides having a phenylseleno group in the 2′-, 3′-, and 5′-positions took place upon oxidation with MCPBA in CH2Cl2 followed by treatment with acid anhydrides to yield α-acyloxyselenides. |
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