Synthesis of cis-(1-->3)-glycosides of allyl 2-acetamido-4,6-O-benzylidene-2-deoxy-alpha-D-glucopyranoside |
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Authors: | Madaj Janusz Jankowska Magdalena Wiśniewski Andrzej |
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Institution: | Department of Chemistry, Sugar Chemistry Group, University of Gdańsk, ul. Sobieskiego 18, PL-80-952 Gdańsk, Poland. januszm@chemik.chem.univ.gda.pl |
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Abstract: | Syntheses of allyl 2,3,4-tri-O-benzyl-alpha-D-gluco- and D-galactopyranosyluronate-(1-->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-alpha-D-glucopyranoside via oxidation of the hydroxymethyl group of allyl 2,3,4-tri-O-benzyl-alpha-D-gluco- and D-galactopyranosyl-(1-->3)-2-acetamido-4,6-O-benzylidene-2-deoxy-alpha-D-glucopyranoside under Jones conditions are described. Structures of the title compounds were confirmed by (1)H and (13)C NMR spectroscopy. |
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Keywords: | Uronic acid d-glucopyranose" target="_blank">2-Acetamido-2-deoxy-d-glucopyranose Jones oxidation 1H and 13C NMR spectroscopy |
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