Slow relaxation of the magnetization in high-nuclearity Ln-complexes |
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| Authors: | Xiaojun Gu Rodolphe Clérac Ahmad Houri Dongfeng Xue |
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| Institution: | 1. State Key Laboratory of Fine Chemicals, Department of Materials Science and Chemical Engineering, Dalian University of Technology, Dalian 116012, PR China;2. Université Bordeaux 1, CNRS, Centre de Recherche Paul, Pascal-UPR8641, 115 Avenue du, Dr. Albert Schweitzer, 33600 Pessac, France |
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| Abstract: | By the surface modification strategy, a novel high-nuclearity lanthanide complex with a discrete structure, Er26I(μ3-OH)20(μ3-O)6(NO3)9(IN)33(OH)3(H2O)33 (noted Er26, HIN = isonicotinic acid), has been prepared under hydrothermal conditions. The magnetic properties of Er26 and two analogue dysprosium assemblies Dy30I(μ3-OH)24(μ3-O)6(NO3)9(IN)41(OH)3(H2O)38 (noted Dy26-I) and Dy26I(μ3-OH)20(μ3-O)6(NO3)9(IN)31.25(OH)4.75(H2O)41.75 (noted Dy26-II) have been studied. The results show that the slow relaxation of the magnetization is newly found in Dy26-I constructed from {Dy26} and {Dy4} cluster units. The {Dy4} units in Dy26-I, the relative orientation of the complex or the inter-molecular interactions between {Dy26} cores might play an important role in the origin of this magnetic behavior. |
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