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On the Reaction of Superoxide With DMPO/*OOH
Authors:Garry R. Buettner
Affiliation: a ESR Center, EMRB 58, The University of Iowa, Iowa City, IA, USA
Abstract:A kinetic model has been used to estimate the rate constant for the reaction of superoxide (O2/OOH) with the superoxide spin adduct of 5.5-dimethylpyrroline-N-oxide. DMPO/OOH. This rate constant is estimated to be 4.9 (± 2.2) × 106 M-1 s-1, pH 7.4 and 25°C.
Keywords:Spin trapping  5.5-dimethylpyrroline-N-oxide  superoxide  free radical
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