Myoglobin-catalyzed epoxidation of styrene in organic solvents accelerated by bioimprinting |
| |
| Authors: | Shinji Ozawa Alexander M Klibanov |
| |
| Institution: | (1) Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA |
| |
| Abstract: | Myoglobin imprinted in aqueous solution with ligands binding to its heme iron, followed by lyophilization, catalyzed the epoxidation of styrene with H2O2or tert-butyl hydroperoxide in organic solvents much faster than the non-imprinted protein under otherwise the same conditions. |
| |
| Keywords: | bioimprinting epoxidation myoglobin non-aqueous biocatalysis organic solvents |
| 本文献已被 SpringerLink 等数据库收录！ |
