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Optical analysis of Sr3Gd(PO4)3:Pr3+ phosphors for lighting applications
Authors:P Shahab Khan  B C Jamalaiah
Institution:1. Research Scholar, Department of Physics, Jawaharlal Nehru Technological University, Anantapur, Andhra Pradesh, India

Department of Physics, Rajeev Gandhi Memorial College of Engineering and Technology (Autonomous), Nandyal, Andhra Pradesh, India;2. Department of Physics, Rajeev Gandhi Memorial College of Engineering and Technology (Autonomous), Nandyal, Andhra Pradesh, India

Abstract:A series of praseodymium (Pr3+) ion activated Sr3Gd(1?x)(PO4)3:xPr3+ (0 ≤ x ≤ 2.0 mol%) phosphors were prepared and their structural, compositional and luminescence properties were investigated. The X-ray diffraction profiles indicate that the studied phosphors crystallized into body centred cubic structure and the Pr3+ ions have no influence on Sr3Gd(PO4)3 phase. The high-resolution scanning electron microscopy images show the agglomeration of particles that are inter-connected and form irregular shape Sr3Gd(PO4)3 structures. The excitation transitions corresponding to Pr3+:3H43P2,1,0 transitions at 445, 471 and 483 nm, respectively, matched well with the emission of blue-light-emitting diode (LED) chip. The emission spectra show strong reddish-orange luminescence through 1D23H4 transition when excited at 445 nm blue wavelength. The synthesized phosphors have the potential to be used as reddish-orange lighting devices.
Keywords:lighting devices  luminescence properties  modified citrate sol–gel combustion  Sr3Gd(PO4)3 phosphors  tri-valent praseodymium
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