Eight-connected coordination framework supported by tricopper(II) secondary building blocks |
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| Authors: | Andrey B Lysenko |
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| Institution: | Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine |
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| Abstract: | In a series of coordination polymers based upon 4,4′-bitriazole (btr) Cu3Cl2(H2O)2(btr)4]2(ZnCl4)2(Cl3ZnOZnCl3), Cu3Cl2(H2O)2(btr)4](MCl4)2 (M = Cd; Hg), eight-connected metal-organic frameworks related to a CsCl (bcu) structure originate in the functionality of trinuclear copper/chloride ensembles bridged by the organic ligands. Cu3Cl4(btr)4]Cl2 complex adopts simpler 1D polymeric structure also incorporating trinuclear copper/chloride clusters. |
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| Keywords: | Copper Polynuclear complexes Bitriazole Metal-organic frameworks Crystal structures |
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