Characterization of tricarbonyl-chromium(0), -molybdenum(0) and -tungsten(0) complexes with 2,2-para-cyclophane |
| |
| Authors: | F Cristiani D De Filippo P Deplano F Devillanova A Diaz EF Trogu G Verani |
| |
| Institution: | Istituto Chimico Policattedra, Via Ospedale, 72 09100 Cagliari, Italy |
| |
| Abstract: | Complexes of the type M(CO)3(22cy), where M = Cr, Mo, W and 22cy = 2,2-para-cyclophane were prepared and characterised. The i.r., p.m.r., mass spectrography spectra are discussed. The Mo derivative decomposes in solution giving 22cy, Mo(CO)6 and Mo, according to a first order mechanism. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
