Conformational studies on aldonolactones by n.m.r. spectroscopy. Conformations of d-glucono-1,5-lactone and d-mannono-1,5-lactone in solution |
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| Authors: | Zbigniew Wałaszek Derek Horton Irena Ekiel |
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| Affiliation: | Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 U.S.A. |
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| Abstract: | The conformations of d-glucono-1,5-lactone (1) and d-mannono-1,5-lactone (2) in solution were investigated by 1H- and 13C-n.m.r. spectroscopy. Conformational equilibria for 1 and 2 were found to lie strongly in favor of the 4H3(d),gg and B2,5(d),gg conformations, respectively. |
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| Keywords: | To whom inquiries should be addressed |
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