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Chemical and 13C-n.m.r. studies of an arabinogalactan from Larix sibirica L.
Authors:Štefan Karácsonyi  Vladimír Kováčik  Juraj Alföldi  Marta Kubačková
Affiliation:Institute of Chemistry, Slovak Academy of Sciences, 842 38 Bratislava Czechoslovakia
Abstract:An arabinogalactan isolated from the wood of Larix sibirica L. was investigated by methylation analysis, partial hydrolysis, enzymic oxidation, and 13C-n.m.r. spectroscopy. The structural conclusions arrived at by 13C-n.m.r. spectroscopy were consistent with the data from methylation analysis. The polysaccharide is highly branched and similar in structure to those of arabino-3,6-galactans isolated from other Larix species.
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