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Second-order susceptibilities of anisotropic liquid-crystal thin films
Authors:M. Pinnow  G. Marowsky  F. Sieverdes  F. H. Kreuzer  H. Leigeber  A. Miller  P. Spes
Affiliation:(1) Max-Planck-Institut für biophysikalische Chemie, Abt. Laserphysik, Am Faßberg, D-3400 Göttingen, Germany;(2) Consortium für elektrochemische Industrie GmbH, Zentrale Forschungsgesellschaft der Wacker Chemie GmbH, Zielstattstraße 20, D-8000 München 70, Germany
Abstract:Using optical second-harmonic generation, we have measured the anisotropic orientation behavior of liquid crystal (LC) molecules in thin films. A high degree of in-plane anisotropy was obtained by depositing the LC films onto rubbed polyimide-covered substrates. The analysis with respect to the relevant second-order susceptibility tensor components is based upon the experimental results obtained in transmission geometry using different angles of incidence for the separation of isotropic and anisotropic contributions.
Keywords:Second-harmonic generation  liquid crystals  orientation analysis
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