Crystal structure, magnetic properties and Mössbauer studies of [Fe(qsal)2][Ni(dmit)2] |
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| Authors: | Christophe Faulmann Stéphane Dorbes Kane Jacob Gábor Molnár José Antonio Real |
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| Institution: | a Laboratoire de Chimie de Coordination, 205 Route de Narbonne, 31077 Toulouse Cedex, France
b Institut de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, Edificio de Institutos de Paterna, P.O. Box 22085, 46071 Valencia, Spain |
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| Abstract: | A new compound of formula Fe(qsal)2]Ni(dmit)2] (1) has been synthesised, structurally and magnetically characterised (qsalH = N-(8-quinolyl)salicylaldimine, dmit2− = 1,3-dithiol-2-thione-4,5-dithiolato). Its structural features and its magnetic behaviour were compared with those of Fe(qsal)2]-based complexes, and more particularly Fe(qsal)2]Ni(dmit)2] · 2CH3CN. |
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| Keywords: | X-ray crystal structures Mossbauer spectroscopy Spin crossover Metal bisdithiolene complex Magnetic properties Pressure effects |
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