Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe2(C2O4)Cl4(DMF)4 (DMF = dimethylformamide)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe₂(C₂O₄)Cl₄(DMF)₄ (DMF = dimethylformamide)

Authors:	Bin Zhang Yan Zhang

Institution:	^a Organic Solid Laboratory, BNLMS, CMS and Institute of Chemistry, The Chinese Academy of Science, Beijing 100080, PR China ^b Department of Physics, Peking University, Beijing 100871, PR China ^c Laboratoire de Chimie de Coordination Organique, CNRS-UMR7140, Université Louis Pasteur, 4 Rue Blaise Pascal, 67000 Strasbourg Cedex 1, France

Abstract:	An oxalato-bridged binuclear iron(III) compound, Fe₂(C₂O₄)Cl₄(DMF)₄ (DMF = dimethylformamide), was obtained by electrocrystallization for three weeks at 3.4 V and it displays a strong antiferromagnetic interaction of J = −6.74(4) cm⁻¹.

Keywords:	Iron compound Binuclear Oxalate X-ray crystal structure Magnetic property
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