Synthesis and characterization of carbamoyl methyl pyrazole(CMPz) compounds of palladium(II) chloride: The crystal and molecular structure of [PdCl2{C3H3N2CH2CONBu2}2] |
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| Authors: | Shanmugaperumal Kannan Michael GB Drew |
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| Institution: | a Fuel Chemistry Division, Bhabha Atomic Research Center, Mumbai 400 085, India
b School of Chemistry, The University of Reading, P.O. Box 224, Whiteknights, Reading, RG6 6AD, UK |
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| Abstract: | Carbamoyl methyl pyrazole compound of palladium(II) chloride of the type PdCl2L2] (where L = C5H7N2CH2CON(C4H9)2, C5H7N2CH2CON(iC4H9)2, C3H3N2CH2CON(C4H9)2, or C3H3N2CH2CON(iC4H9)2) has been synthesized and characterized by IR and 1H NMR spectroscopy. The structure of the compound PdCl2{C3H3N2CH2CONiBu2}2] has been determined by single crystal X-ray diffraction and shows that the ligands are bonded through the soft pyrazolyl nitrogen atom to the palladium(II) chloride in a trans disposition. |
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| Keywords: | Bi-functional ligand Pyrazole Amide Monodentate Palladium(II) chloride X-ray crystal structure |
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