Excited state properties of Tl2B12H12. Metal-centered photoluminescence |
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| Authors: | Horst Kunkely |
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| Institution: | Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany |
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| Abstract: | The compound Tl2B12H12 which consists of icosahedral  anions and Tl+ cations shows a metal-centered r.t. luminescence at λmax = 530 nm which originates from the lowest-energy sp triplet of Tl+. This emission indicates a considerable covalent interaction between Tl+ and  which is based on the hydridic nature of the boron cluster. |
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| Keywords: | Electronic spectra Metal-centered excited states Photoluminescence Phosphorescence Thallium Borane |
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