The high-energy intraconfigurational spin-forbidden bands in the spectra of quadrate chromium(III) complexes |
| |
| Authors: | CS Williams NC Miller JR Perumareddi |
| |
| Institution: | Department of Chemistry, Florida Atlantic University, 777 Glades Road, Boca Raton, FL 33431, United States |
| |
| Abstract: | The high-energy intraconfigurational spin-forbidden bands expected in the region of 20 000 cm−1 have been uncovered in the spectra of a number of trans-diacidobis(ethylenediamine) chromium(III)complexes. These bands have been fitted to the quadrate components of the cubic transition 4A2g → 2T2g including spin-orbit interaction. Two interconfigurational spin-forbidden bands in the spectrum of trans-Cr(en)2(dmf)2](ClO4)3 have been uncovered and interpretted. |
| |
| Keywords: | Spin-forbidden bands Chromium(III) complexes |
| 本文献已被 ScienceDirect 等数据库收录！ |
