Formation of iron(VI) in ozonalysis of iron(III) in alkaline solution |
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| Authors: | Yurii D. Perfiliev Denis A. Pankratov Sergey K. Dedushenko |
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| Affiliation: | a Department of Chemistry, Moscow State University, 1 Lenin Hills, Moscow 119992, Russia
b Florida Institute of Technology, Chemistry Department, 150 West University Boulevard, Melbourne, FL 32901, USA |
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| Abstract: | Here we report the formation of iron in hexavalent state,  in ozonalysis of iron(III) in alkaline medium. The formation of tetrahedral  ion is confirmed by UV-Visible and Mössbauer spectroscopic techniques. The value of isomer shift, δ, of the tetra-oxy anion is consistent with known δ values for various salts of iron(VI) ion. |
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| Keywords: | Iron(VI) Iron(III) Ozone Mö ssbauer spectroscopy |
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