1. Smithsonian Institution, Department of Botany, Washington, DC 20560, U.S.A.
Abstract:
The aerial parts of Helenium amarum afforded, in addition to compounds reported previously, several known sesquiterpene lactones as well as some new ones, two pseudoguaianolides and a complex mixture of guaianolide α-arabinopyranosides, which differed in the position of the double bond, the configuration at C-8 and the position of an acetate group in the sugar moiety. Furthermore seco-caryophyllenes and phenylpropane derivatives were isolated. The structures were elucidated by spectroscopic methods and few chemical transformations.