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Guaianolides and chromenes from Calea species
Authors:Alfonso G Ober  Lowell E Urbatsch  Nikolaus H Fischer
Institution:1. Department of Botany, Louisiana State University, Baton Rouge, LA 70803, U.S.A.
Abstract:Chemical analysis of Calea berteriana yielded, besides the known flavonoid acacetin and the sesquiterpene lactone calbertolide C, three new guaianolides, desacyl-8-tiglylsubcordatolide A and 8-epi-8-tiglylrupicolins A and B. C. prunifolia provided acacetin, calbertolide C, desacyl-8-tiglylsubcordatolide A, and two new chromenes, prunichromenes A and B. From C. solidaginea acacetin, heliangine, calbertolide C, 8-epi-8-tiglylrupicolin A and desacyl-8-tiglylsubcordatolide A were isolated. The structures of the new compounds were established by chemical and spectral methods.
Keywords:Asteraceae  Heliantheae  sesquiterpene lactones  guaianolides  heliangolides  2  2-dimethylchromenes
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