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Application of fast atom bombardment mass spectrometry to chlorogenic acids
Authors:Akiyo Sakushima  Sueo Hisada  Sansei Nishibe  Hans Brandenderger
Affiliation:1. Department of Forensic Chemistry, University of Zürich, CH-8028 Zürich, Switzerland
Abstract:The technique of positive- and negative-ion fast atom bombardment mass spectrometry has been shown to be capable of producing molecular mass and useful fragmentation information for the structural elucidation of chlorogenic acids. The mass spectra of chlorogenic acid and the related compounds 3′-O-methylchlorogenic acid, neochlorogenic acid, 4,5-dicaffeoyl quinic acid and 1,5-dicaffeoyl quinic acid are compared with those obtained by electron impact mass spectrometry.
Keywords:Chlorogenic acids  chlorogenic acid  neochlorogenic acid  4,5- dicaffeoyl quinic acid  1,5-dicaffeoyl quinic acid  electron impact mass specrometry  positive-ion fast atom bombardment mass spectrometry  negative-ion fast atom bombardment mass spectrometry.
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