Oxoperoxofluoromolybdate(VI) complexes. The first synthesis of oxodiperoxofluoromolybdate(VI) complexes |
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| Affiliation: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India |
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| Abstract: | A number of oxoperoxofluoromolybdate(VI) complexes, viz. M2[MoO(O2)F4] and M2[MoO(O2)2F2] where M = K and NH4 and K[MoO(O2)2F]·2H2O have been synthesised by various methods. The infrared spectra suggest that the peroxide groups are bonded to the molybdenum centre in a triangular bidentate manner. |
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